Potassium N-heterobiaryltrifluoroborates were successfully prepared via a selective Cu-catalyzed C-N coupling reaction. The BF3K moiety was well tolerated under the reaction conditions involving CuI and dimethylethylenediamine (DMEDA) in the presence of DMSO. The Pd-catalyzed Suzuki-Miyaura cross couplings of potassium N-heterobiaryltrifluoroborates with bromoarenes were studied to prepare the N-heterotriaryl compounds. Moreover, homocoupling, iodination, and hydroxylation of potassium N-heterobiaryltrifluoroborates provided the corresponding products in high yields.
|Number of pages||7|
|Journal||Bulletin of the Korean Chemical Society|
|Publication status||Published - 2013 Jan 20|
- Chan-Lam coupling
- Cu-catalyzed C-N coupling
- Potassium N-heterobiaryltrifluoroborates
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