Glucose-mediated hydrothermal synthesis and gas sensing characteristics of WO3 hollow microspheres

Choong Yong Lee; Sun Jung Kim; In Sung Hwang; Jong Heun Lee

doi:10.1016/j.snb.2009.08.031

Glucose-mediated hydrothermal synthesis and gas sensing characteristics of WO₃ hollow microspheres

Choong Yong Lee, Sun Jung Kim, In Sung Hwang, Jong Heun Lee

Research output: Contribution to journal › Article › peer-review

99 Citations (Scopus)

Abstract

Tungsten-coated carbon microspheres were prepared by one-pot hydrothermal reaction of an aqueous solution containing glucose and sodium tungstate. The spheres were converted into WO₃ hollow microspheres by the decomposition of their core carbon. The [glucose]/[sodium tungstate] ratio of the stock solution determined not only the morphology of the precursors but also the phase of the powders after calcination. The WO₃ hollow microspheres showed a higher gas response and more selective detection of 0.5-2.5 ppm NO₂ than WO₃ solid and nano-porous microspheres did. The enhanced NO₂ sensing characteristics are explained in relation to the surface area, pore volume, and hollow morphology.

Original language	English
Pages (from-to)	236-242
Number of pages	7
Journal	Sensors and Actuators, B: Chemical
Volume	142
Issue number	1
DOIs	https://doi.org/10.1016/j.snb.2009.08.031
Publication status	Published - 2009 Oct 12

Keywords

Carbon template
Hollow microspheres
NO sensor
WO

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Instrumentation
Condensed Matter Physics
Surfaces, Coatings and Films
Metals and Alloys
Electrical and Electronic Engineering
Materials Chemistry

Access to Document

10.1016/j.snb.2009.08.031

Cite this

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title = "Glucose-mediated hydrothermal synthesis and gas sensing characteristics of WO3 hollow microspheres",

abstract = "Tungsten-coated carbon microspheres were prepared by one-pot hydrothermal reaction of an aqueous solution containing glucose and sodium tungstate. The spheres were converted into WO3 hollow microspheres by the decomposition of their core carbon. The [glucose]/[sodium tungstate] ratio of the stock solution determined not only the morphology of the precursors but also the phase of the powders after calcination. The WO3 hollow microspheres showed a higher gas response and more selective detection of 0.5-2.5 ppm NO2 than WO3 solid and nano-porous microspheres did. The enhanced NO2 sensing characteristics are explained in relation to the surface area, pore volume, and hollow morphology.",

keywords = "Carbon template, Hollow microspheres, NO sensor, WO",

author = "Lee, {Choong Yong} and Kim, {Sun Jung} and Hwang, {In Sung} and Lee, {Jong Heun}",

note = "Funding Information: This work was supported by KOSEF NRL program grant funded by the Korean Government (MEST) (No. R0A-2008-000-20032-0 ) and a grant from the Fundamental R&D program for Core Technology of Materials ( M2008010013 ) funded by the Ministry of Knowledge Economy , Republic of Korea. ",

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AU - Lee, Choong Yong

AU - Kim, Sun Jung

AU - Hwang, In Sung

AU - Lee, Jong Heun

N1 - Funding Information: This work was supported by KOSEF NRL program grant funded by the Korean Government (MEST) (No. R0A-2008-000-20032-0 ) and a grant from the Fundamental R&D program for Core Technology of Materials ( M2008010013 ) funded by the Ministry of Knowledge Economy , Republic of Korea.

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N2 - Tungsten-coated carbon microspheres were prepared by one-pot hydrothermal reaction of an aqueous solution containing glucose and sodium tungstate. The spheres were converted into WO3 hollow microspheres by the decomposition of their core carbon. The [glucose]/[sodium tungstate] ratio of the stock solution determined not only the morphology of the precursors but also the phase of the powders after calcination. The WO3 hollow microspheres showed a higher gas response and more selective detection of 0.5-2.5 ppm NO2 than WO3 solid and nano-porous microspheres did. The enhanced NO2 sensing characteristics are explained in relation to the surface area, pore volume, and hollow morphology.

AB - Tungsten-coated carbon microspheres were prepared by one-pot hydrothermal reaction of an aqueous solution containing glucose and sodium tungstate. The spheres were converted into WO3 hollow microspheres by the decomposition of their core carbon. The [glucose]/[sodium tungstate] ratio of the stock solution determined not only the morphology of the precursors but also the phase of the powders after calcination. The WO3 hollow microspheres showed a higher gas response and more selective detection of 0.5-2.5 ppm NO2 than WO3 solid and nano-porous microspheres did. The enhanced NO2 sensing characteristics are explained in relation to the surface area, pore volume, and hollow morphology.

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