Gold catalyst reactivity for CO2 electro-reduction: From nano particle to layer

Eduardus Budi Nursanto; Hyo Sang Jeon; Cheonghee Kim; Michael Shincheon Jee; Jai Hyun Koh; Yun Jeong Hwang; Byoung Koun Min

doi:10.1016/j.cattod.2015.05.017

Gold catalyst reactivity for CO₂ electro-reduction: From nano particle to layer

Eduardus Budi Nursanto, Hyo Sang Jeon, Cheonghee Kim, Michael Shincheon Jee, Jai Hyun Koh, Yun Jeong Hwang, Byoung Koun Min

GREEN SCHOOL (Graduate School of Energy and Environment)

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

CO₂ electro-reduction is a promising method for sustainable production of carbon fuels as well as valuable chemicals. Herein, we investigated a direct electro-catalytic CO₂ conversion to CO by nanostructured gold catalysts from the small nanoparticles to aggregated clusters to layered film. The selectivity of CO formation was found to increase as the gold amount increased and it reached a saturation point of ∼78% (-0.59 V vs. RHE) at the morphological transition from aggregated cluster to layered film. Furthermore, the ∼4 nm gold nanoparticle exhibited a remarkable CO formation mass activity value at 166.1 A/g (-0.59 V vs. RHE).

Original language	English
Pages (from-to)	107-111
Number of pages	5
Journal	Catalysis Today
Volume	260
DOIs	https://doi.org/10.1016/j.cattod.2015.05.017
Publication status	Published - 2016 Feb 1

Keywords

CO electro-reduction
E-beam deposition
Gold catalysts

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1016/j.cattod.2015.05.017

Cite this

@article{77c813d6dced4a099b200572495e5a99,

title = "Gold catalyst reactivity for CO2 electro-reduction: From nano particle to layer",

abstract = "CO2 electro-reduction is a promising method for sustainable production of carbon fuels as well as valuable chemicals. Herein, we investigated a direct electro-catalytic CO2 conversion to CO by nanostructured gold catalysts from the small nanoparticles to aggregated clusters to layered film. The selectivity of CO formation was found to increase as the gold amount increased and it reached a saturation point of ∼78% (-0.59 V vs. RHE) at the morphological transition from aggregated cluster to layered film. Furthermore, the ∼4 nm gold nanoparticle exhibited a remarkable CO formation mass activity value at 166.1 A/g (-0.59 V vs. RHE).",

keywords = "CO electro-reduction, E-beam deposition, Gold catalysts",

author = "Nursanto, {Eduardus Budi} and Jeon, {Hyo Sang} and Cheonghee Kim and Jee, {Michael Shincheon} and Koh, {Jai Hyun} and Hwang, {Yun Jeong} and Min, {Byoung Koun}",

note = "Funding Information: “This work was supported by the program of the Korea Institute of Science and Technology (KIST) and also supported by the Korea Center for Artificial Photosynthesis (KCAP) located in Sogang University funded by the Minister of Science, ICT and Future Planning (MSIP) through the National Research Foundation of Korea (No. 2014M1A2A2070004 )”. Publisher Copyright: {\textcopyright} 2015 Elsevier B.V. All rights reserved.",

year = "2016",

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doi = "10.1016/j.cattod.2015.05.017",

language = "English",

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T2 - From nano particle to layer

AU - Nursanto, Eduardus Budi

AU - Jeon, Hyo Sang

AU - Kim, Cheonghee

AU - Jee, Michael Shincheon

AU - Koh, Jai Hyun

AU - Hwang, Yun Jeong

AU - Min, Byoung Koun

N1 - Funding Information: “This work was supported by the program of the Korea Institute of Science and Technology (KIST) and also supported by the Korea Center for Artificial Photosynthesis (KCAP) located in Sogang University funded by the Minister of Science, ICT and Future Planning (MSIP) through the National Research Foundation of Korea (No. 2014M1A2A2070004 )”. Publisher Copyright: © 2015 Elsevier B.V. All rights reserved.

PY - 2016/2/1

Y1 - 2016/2/1

N2 - CO2 electro-reduction is a promising method for sustainable production of carbon fuels as well as valuable chemicals. Herein, we investigated a direct electro-catalytic CO2 conversion to CO by nanostructured gold catalysts from the small nanoparticles to aggregated clusters to layered film. The selectivity of CO formation was found to increase as the gold amount increased and it reached a saturation point of ∼78% (-0.59 V vs. RHE) at the morphological transition from aggregated cluster to layered film. Furthermore, the ∼4 nm gold nanoparticle exhibited a remarkable CO formation mass activity value at 166.1 A/g (-0.59 V vs. RHE).

AB - CO2 electro-reduction is a promising method for sustainable production of carbon fuels as well as valuable chemicals. Herein, we investigated a direct electro-catalytic CO2 conversion to CO by nanostructured gold catalysts from the small nanoparticles to aggregated clusters to layered film. The selectivity of CO formation was found to increase as the gold amount increased and it reached a saturation point of ∼78% (-0.59 V vs. RHE) at the morphological transition from aggregated cluster to layered film. Furthermore, the ∼4 nm gold nanoparticle exhibited a remarkable CO formation mass activity value at 166.1 A/g (-0.59 V vs. RHE).

KW - CO electro-reduction

KW - E-beam deposition

KW - Gold catalysts

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