Graphene Quantum Sheet Catalyzed Silicon Photocathode for Selective CO2 Conversion to CO

Ki Dong Yang, Yoonhoo Ha, Uk Sim, Junghyun An, Chan Woo Lee, Kyoungsuk Jin, Younghye Kim, Jimin Park, Jung Sug Hong, Jun Ho Lee, Hye Eun Lee, Hui Yun Jeong, Hyungjun Kim, Ki Tae Nam

Research output: Contribution to journalArticlepeer-review

53 Citations (Scopus)

Abstract

The reduction of carbon dioxide (CO2) into chemical feedstock is drawing increasing attention as a prominent method of recycling atmospheric CO2. Although many studies have been devoted in designing an efficient catalyst for CO2 conversion with noble metals, low selectivity and high energy input still remain major hurdles. One possible solution is to use the combination of an earth-abundant electrocatalyst with a photoelectrode powered by solar energy. Herein, for the first time, a p-type silicon nanowire with nitrogen-doped graphene quantum sheets (N-GQSs) as heterogeneous electrocatalyst for selective CO production is demonstrated. The photoreduction of CO2 into CO is achieved at a potential of -1.53 V versus Ag/Ag+, providing 0.15 mA cm-2 of current density, which is 130 mV higher than that of a p-type Si nanowire decorated with well-known Cu catalyst. The faradaic efficiency for CO is 95%, demonstrating significantly improved selectivity compared with that of bare planar Si. The density functional theory (DFT) calculations are performed, which suggest that pyridinic N acts as the active site and band alignment can be achieved for N-GQSs larger than 3 nm. The demonstrated high efficiency of the catalytic system provides new insights for the development of nonprecious, environmentally benign CO2 utilization.

Original languageEnglish
Pages (from-to)233-242
Number of pages10
JournalAdvanced Functional Materials
Volume26
Issue number2
DOIs
Publication statusPublished - 2016 Jan 13
Externally publishedYes

Keywords

  • carbon dioxide reduction
  • carbon quantum sheets
  • photovoltaic devices

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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