TY - JOUR
T1 - Growth mechanism of In(OH)3 nanocubes during hydrothermal reaction
AU - Kim, Hae Ryong
AU - Lee, Sung Bo
AU - Kim, Doh Yeon
AU - Lee, Jong Heun
N1 - Funding Information:
This work was supported by Grant no. R01-2005-000-10648-0 (2005) from the Basic Research Program of the Korea Science and Engineering Foundation and by Korea Science and Engineering Foundation (KOSEF) grant funded by the Korea government (MEST) (No. R0A-2008-000-20032-0).
Copyright:
Copyright 2008 Elsevier B.V., All rights reserved.
PY - 2008/8/1
Y1 - 2008/8/1
N2 - This study examined the growth mechanism of In(OH)3 nanocubes formed during the hydrothermal reaction of a solution containing In(NO3)3·6H2O, NaOH, and H2O2. Regardless of the pH of the stock solution, an abnormal growth behavior was detected i.e. only a few particles grew to a very large size. However, the mean edge lengths of the nanocubes decreased significantly from 100-450 to 20-70 nm with increasing pH of the stock solution from 4 to 8.8. This was attributed to the active nucleation of In(OH)3 nanocubes at pH 8.8 and the limitation of their growth due to the restricted source materials. The growth of In(OH)3 nanocubes was explained in terms of a two-dimensional nucleation and growth mechanism.
AB - This study examined the growth mechanism of In(OH)3 nanocubes formed during the hydrothermal reaction of a solution containing In(NO3)3·6H2O, NaOH, and H2O2. Regardless of the pH of the stock solution, an abnormal growth behavior was detected i.e. only a few particles grew to a very large size. However, the mean edge lengths of the nanocubes decreased significantly from 100-450 to 20-70 nm with increasing pH of the stock solution from 4 to 8.8. This was attributed to the active nucleation of In(OH)3 nanocubes at pH 8.8 and the limitation of their growth due to the restricted source materials. The growth of In(OH)3 nanocubes was explained in terms of a two-dimensional nucleation and growth mechanism.
KW - A1. Crystal morphology
KW - A1. Growth models
KW - A1. Nanostructures
KW - A2. Hydrothermal crystal growth
KW - B1. Inorganic compounds
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U2 - 10.1016/j.jcrysgro.2008.06.022
DO - 10.1016/j.jcrysgro.2008.06.022
M3 - Article
AN - SCOPUS:48049095936
VL - 310
SP - 3896
EP - 3900
JO - Journal of Crystal Growth
JF - Journal of Crystal Growth
SN - 0022-0248
IS - 16
ER -