Guest-dependent self-assembly of (R,R)-2,3-diphenylsuccinic acids

formation of a cyclotetrameric chiral square

Kyung Seok Jeong, Bohyung Lee, Jaheon Kim, Nakcheol Jeong

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

A chiral crystalline inclusion complex containing four molecules of (+)-(R,R)-1 and one molecule of diethyl ether was grown from diethyl ether with a diffusion of hexane, and its structure was determined by X-ray diffraction. Since this guest-dependent self-assembled cage was presumed to be chiral with D4 symmetry, its potential as an enantiomer separator was examined.

Original languageEnglish
Pages (from-to)549-552
Number of pages4
JournalCrystEngComm
Volume11
Issue number4
DOIs
Publication statusPublished - 2009 Mar 31

Fingerprint

diethyl ether
Ether
Self assembly
self assembly
Ethers
acids
Molecules
Acids
Enantiomers
enantiomers
Hexanes
separators
Hexane
Separators
molecules
inclusions
Crystalline materials
X ray diffraction
symmetry
diffraction

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Guest-dependent self-assembly of (R,R)-2,3-diphenylsuccinic acids : formation of a cyclotetrameric chiral square. / Jeong, Kyung Seok; Lee, Bohyung; Kim, Jaheon; Jeong, Nakcheol.

In: CrystEngComm, Vol. 11, No. 4, 31.03.2009, p. 549-552.

Research output: Contribution to journalArticle

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