Guest-dependent self-assembly of (R,R)-2,3-diphenylsuccinic acids:formation of a cyclotetrameric chiral square

Kyung Seok Jeong; Bohyung Lee; Jaheon Kim; Nakcheol Jeong

doi:10.1039/b819756c

Guest-dependent self-assembly of (R,R)-2,3-diphenylsuccinic acids:formation of a cyclotetrameric chiral square

Kyung Seok Jeong, Bohyung Lee, Jaheon Kim, Nakcheol Jeong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A chiral crystalline inclusion complex containing four molecules of (+)-(R,R)-1 and one molecule of diethyl ether was grown from diethyl ether with a diffusion of hexane, and its structure was determined by X-ray diffraction. Since this guest-dependent self-assembled cage was presumed to be chiral with D₄ symmetry, its potential as an enantiomer separator was examined.

Original language	English
Pages (from-to)	549-552
Number of pages	4
Journal	CrystEngComm
Volume	11
Issue number	4
DOIs	https://doi.org/10.1039/b819756c
Publication status	Published - 2009

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Guest-dependent self-assembly of (R,R)-2,3-diphenylsuccinic acids:formation of a cyclotetrameric chiral square",

abstract = "A chiral crystalline inclusion complex containing four molecules of (+)-(R,R)-1 and one molecule of diethyl ether was grown from diethyl ether with a diffusion of hexane, and its structure was determined by X-ray diffraction. Since this guest-dependent self-assembled cage was presumed to be chiral with D4 symmetry, its potential as an enantiomer separator was examined.",

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AU - Jeong, Kyung Seok

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AU - Kim, Jaheon

AU - Jeong, Nakcheol

PY - 2009

Y1 - 2009

N2 - A chiral crystalline inclusion complex containing four molecules of (+)-(R,R)-1 and one molecule of diethyl ether was grown from diethyl ether with a diffusion of hexane, and its structure was determined by X-ray diffraction. Since this guest-dependent self-assembled cage was presumed to be chiral with D4 symmetry, its potential as an enantiomer separator was examined.

AB - A chiral crystalline inclusion complex containing four molecules of (+)-(R,R)-1 and one molecule of diethyl ether was grown from diethyl ether with a diffusion of hexane, and its structure was determined by X-ray diffraction. Since this guest-dependent self-assembled cage was presumed to be chiral with D4 symmetry, its potential as an enantiomer separator was examined.

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Guest-dependent self-assembly of (R,R)-2,3-diphenylsuccinic acids:formation of a cyclotetrameric chiral square

Abstract

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