Hemi-core@frame AuCu@IrNi nanocrystals as active and durable bifunctional catalysts for the water splitting reaction in acidic media

Jongsik Park, Songa Choi, Aram Oh, Haneul Jin, Jinwhan Joo, Hionsuck Baik, Kwangyeol Lee

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Highly efficient and economically sustainable hydrogen production via electrocatalytic water splitting can be realized by the advent of active and durable electrocatalysts toward the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Multimetallic nanoframe structures have received great attention as promising electrocatalysts for these reactions, because their inherent high surface area and tunable surface energy states are beneficial to the electrocatalyst performance. We envisaged that the stability and activity of multimetallic nanoframe catalysts could be simultaneously augmented by introducing an additional structural feature of activity-enhancing lattice mismatch via formation of a structure-fortifying core-shell structure. Herein, we successfully demonstrate that hemi-core@frame AuCu@IrNi nanocrystals, possessing structural features of both nanoframe and core-shell, are active and durable bifunctional catalysts toward both the OER and HER under acidic conditions. The hemicore@frame AuCu@IrNi nanocrystals exhibit superior efficient electrocatalytic performance toward the overall water splitting reaction, and show 355 mV overpotential at the current density of 10 mA cm -2 in a 0.5 M H 2 SO 4 electrolyte. The robustness of the catalysts was also verified through the long-term stability test.

Original languageEnglish
Pages (from-to)727-734
Number of pages8
JournalNanoscale Horizons
Volume4
Issue number3
DOIs
Publication statusPublished - 2019 May 1

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Electrocatalysts
Nanocrystals
Catalysts
Water
Hydrogen
Oxygen
Lattice mismatch
Hydrogen production
Interfacial energy
Electron energy levels
Electrolytes
Current density

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Hemi-core@frame AuCu@IrNi nanocrystals as active and durable bifunctional catalysts for the water splitting reaction in acidic media. / Park, Jongsik; Choi, Songa; Oh, Aram; Jin, Haneul; Joo, Jinwhan; Baik, Hionsuck; Lee, Kwangyeol.

In: Nanoscale Horizons, Vol. 4, No. 3, 01.05.2019, p. 727-734.

Research output: Contribution to journalArticle

Park, Jongsik ; Choi, Songa ; Oh, Aram ; Jin, Haneul ; Joo, Jinwhan ; Baik, Hionsuck ; Lee, Kwangyeol. / Hemi-core@frame AuCu@IrNi nanocrystals as active and durable bifunctional catalysts for the water splitting reaction in acidic media. In: Nanoscale Horizons. 2019 ; Vol. 4, No. 3. pp. 727-734.
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