Abstract
Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).
| Original language | English |
|---|---|
| Pages (from-to) | 3852-3854 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 41 |
| Issue number | 20 |
| DOIs | |
| Publication status | Published - 2002 Oct 18 |
Keywords
- Asymmetric catalysis
- Heterogeneous catalysis
- P ligands
- Palladium
- Polymers
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Song, C. E., Yang, J. W., Roh, E. J., Lee, S. G., Ahn, J. H., & Han, H. (2002). Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands. Angewandte Chemie - International Edition, 41(20), 3852-3854. https://doi.org/10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I