Abstract
Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).
| Original language | English |
|---|---|
| Pages (from-to) | 3852-3854 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 41 |
| Issue number | 20 |
| DOIs | |
| Publication status | Published - 2002 Oct 18 |
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Keywords
- Asymmetric catalysis
- Heterogeneous catalysis
- P ligands
- Palladium
- Polymers
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands. / Song, Choong Eui; Yang, Jung Woon; Roh, Eun Joo; Lee, Sang Gi; Ahn, Jou Hyeon; Han, Hogyu.
In: Angewandte Chemie - International Edition, Vol. 41, No. 20, 18.10.2002, p. 3852-3854.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands
AU - Song, Choong Eui
AU - Yang, Jung Woon
AU - Roh, Eun Joo
AU - Lee, Sang Gi
AU - Ahn, Jou Hyeon
AU - Han, Hogyu
PY - 2002/10/18
Y1 - 2002/10/18
N2 - Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).
AB - Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).
KW - Asymmetric catalysis
KW - Heterogeneous catalysis
KW - P ligands
KW - Palladium
KW - Polymers
UR - http://www.scopus.com/inward/record.url?scp=0037131591&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037131591&partnerID=8YFLogxK
U2 - 10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I
DO - 10.1002/1521-3773(20021018)41:20<3852::AID-ANIE3852>3.0.CO;2-I
M3 - Article
C2 - 12386868
AN - SCOPUS:0037131591
VL - 41
SP - 3852
EP - 3854
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 20
ER -