Abstract
Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).
Original language | English |
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Pages (from-to) | 3852-3854 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 41 |
Issue number | 20 |
DOIs | |
Publication status | Published - 2002 Oct 18 |
Keywords
- Asymmetric catalysis
- Heterogeneous catalysis
- P ligands
- Palladium
- Polymers
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)