Heterogeneous Pd-catalyzed asymmetric allylic substitution using resin-supported Trost-type bisphosphane ligands

Choong Eui Song, Jung Woon Yang, Eun Joo Roh, Sang Gi Lee, Jou Hyeon Ahn, Hogyu Han

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

Easy recovery and reutilization of the catalyst in consecutive reactions: These are the advantages offered by a new class of polymer-bound Trost-type ligands (see Figure; is a polystyrene-based resin or JandaJEL). A complex is formed with [{(η3-C3H5)PdCl}2] that catalyzes asymmetric allylic substitutions with excellent activity and enantioselectivity (up to 99% ee).

Original languageEnglish
Pages (from-to)3852-3854
Number of pages3
JournalAngewandte Chemie - International Edition
Volume41
Issue number20
DOIs
Publication statusPublished - 2002 Oct 18

Keywords

  • Asymmetric catalysis
  • Heterogeneous catalysis
  • P ligands
  • Palladium
  • Polymers

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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