Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran catalyzed by vanadium supported activated carbon in MIBK, extracting solvent for HMF

Churchil A. Antonyraj; Bora Kim; Yongjin Kim; Seunghan Shin; Kwan Young Lee; Il Kim; Jin Ku Cho

doi:10.1016/j.catcom.2014.08.008

Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran catalyzed by vanadium supported activated carbon in MIBK, extracting solvent for HMF

Churchil A. Antonyraj, Bora Kim, Yongjin Kim, Seunghan Shin, Kwan Young Lee, Il Kim, Jin Ku Cho

Department of Chemical and Biological Engineering

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using molecular oxygen and vanadium catalyst onto activated carbon in MIBK, extracting solvent for HMF, is described. Highly stable V₂O₅ supported on activated carbon catalyst was synthesized using V^{3 +} (VCl₃) precursor and confirmed by XPS analysis, which found to be highly active. A maximum HMF conversion of > 95% with > 96% DFF selectivity was achieved and this heterogeneous catalyst could be used 4 times without any significant loss of activity.

Original language	English
Pages (from-to)	64-68
Number of pages	5
Journal	Catalysis Communications
Volume	57
DOIs	https://doi.org/10.1016/j.catcom.2014.08.008
Publication status	Published - 2014 Dec 5

Keywords

2,5-Diformylfuran (DFF)
5-Hydroxymethyl-2-furfural (HMF)
Extracting solvent
Methyl isobutyl ketone (MIBK)
Oxidation
Vanadium

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Process Chemistry and Technology

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Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran catalyzed by vanadium supported activated carbon in MIBK, extracting solvent for HMF. / Antonyraj, Churchil A.; Kim, Bora; Kim, Yongjin; Shin, Seunghan; Lee, Kwan Young; Kim, Il; Cho, Jin Ku.

In: Catalysis Communications, Vol. 57, 05.12.2014, p. 64-68.

Research output: Contribution to journal › Article › peer-review

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title = "Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran catalyzed by vanadium supported activated carbon in MIBK, extracting solvent for HMF",

abstract = "Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using molecular oxygen and vanadium catalyst onto activated carbon in MIBK, extracting solvent for HMF, is described. Highly stable V2O5 supported on activated carbon catalyst was synthesized using V3 + (VCl3) precursor and confirmed by XPS analysis, which found to be highly active. A maximum HMF conversion of > 95% with > 96% DFF selectivity was achieved and this heterogeneous catalyst could be used 4 times without any significant loss of activity.",

keywords = "2,5-Diformylfuran (DFF), 5-Hydroxymethyl-2-furfural (HMF), Extracting solvent, Methyl isobutyl ketone (MIBK), Oxidation, Vanadium",

author = "Antonyraj, {Churchil A.} and Bora Kim and Yongjin Kim and Seunghan Shin and Lee, {Kwan Young} and Il Kim and Cho, {Jin Ku}",

note = "Funding Information: This work was supported by the Korea Ministry of Environment as “Converging technology project ( 202-091-002 )”. It was also funded by the Ministry of Education, Science and Technology as “Fusion Research Program for Green Technologies ( 2012 M3C1A1054496 )” through the National Research Foundation of Korea. ",

year = "2014",

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doi = "10.1016/j.catcom.2014.08.008",

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journal = "Catalysis Communications",

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AU - Antonyraj, Churchil A.

AU - Kim, Bora

AU - Kim, Yongjin

AU - Shin, Seunghan

AU - Lee, Kwan Young

AU - Kim, Il

AU - Cho, Jin Ku

N1 - Funding Information: This work was supported by the Korea Ministry of Environment as “Converging technology project ( 202-091-002 )”. It was also funded by the Ministry of Education, Science and Technology as “Fusion Research Program for Green Technologies ( 2012 M3C1A1054496 )” through the National Research Foundation of Korea.

PY - 2014/12/5

Y1 - 2014/12/5

N2 - Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using molecular oxygen and vanadium catalyst onto activated carbon in MIBK, extracting solvent for HMF, is described. Highly stable V2O5 supported on activated carbon catalyst was synthesized using V3 + (VCl3) precursor and confirmed by XPS analysis, which found to be highly active. A maximum HMF conversion of > 95% with > 96% DFF selectivity was achieved and this heterogeneous catalyst could be used 4 times without any significant loss of activity.

AB - Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using molecular oxygen and vanadium catalyst onto activated carbon in MIBK, extracting solvent for HMF, is described. Highly stable V2O5 supported on activated carbon catalyst was synthesized using V3 + (VCl3) precursor and confirmed by XPS analysis, which found to be highly active. A maximum HMF conversion of > 95% with > 96% DFF selectivity was achieved and this heterogeneous catalyst could be used 4 times without any significant loss of activity.

KW - 2,5-Diformylfuran (DFF)

KW - 5-Hydroxymethyl-2-furfural (HMF)

KW - Extracting solvent

KW - Methyl isobutyl ketone (MIBK)

KW - Oxidation

KW - Vanadium

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