Abstract
Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using molecular oxygen and vanadium catalyst onto activated carbon in MIBK, extracting solvent for HMF, is described. Highly stable V2O5 supported on activated carbon catalyst was synthesized using V3 + (VCl3) precursor and confirmed by XPS analysis, which found to be highly active. A maximum HMF conversion of > 95% with > 96% DFF selectivity was achieved and this heterogeneous catalyst could be used 4 times without any significant loss of activity.
| Original language | English |
|---|---|
| Pages (from-to) | 64-68 |
| Number of pages | 5 |
| Journal | Catalysis Communications |
| Volume | 57 |
| DOIs | |
| Publication status | Published - 2014 Dec 5 |
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ASJC Scopus subject areas
- Catalysis
- Process Chemistry and Technology
- Chemistry(all)
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Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran catalyzed by vanadium supported activated carbon in MIBK, extracting solvent for HMF. / Antonyraj, Churchil A.; Kim, Bora; Kim, Yongjin; Shin, Seunghan; Lee, Kwan Young; Kim, Il; Cho, Jin Ku.
In: Catalysis Communications, Vol. 57, 05.12.2014, p. 64-68.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran catalyzed by vanadium supported activated carbon in MIBK, extracting solvent for HMF
AU - Antonyraj, Churchil A.
AU - Kim, Bora
AU - Kim, Yongjin
AU - Shin, Seunghan
AU - Lee, Kwan Young
AU - Kim, Il
AU - Cho, Jin Ku
PY - 2014/12/5
Y1 - 2014/12/5
N2 - Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using molecular oxygen and vanadium catalyst onto activated carbon in MIBK, extracting solvent for HMF, is described. Highly stable V2O5 supported on activated carbon catalyst was synthesized using V3 + (VCl3) precursor and confirmed by XPS analysis, which found to be highly active. A maximum HMF conversion of > 95% with > 96% DFF selectivity was achieved and this heterogeneous catalyst could be used 4 times without any significant loss of activity.
AB - Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using molecular oxygen and vanadium catalyst onto activated carbon in MIBK, extracting solvent for HMF, is described. Highly stable V2O5 supported on activated carbon catalyst was synthesized using V3 + (VCl3) precursor and confirmed by XPS analysis, which found to be highly active. A maximum HMF conversion of > 95% with > 96% DFF selectivity was achieved and this heterogeneous catalyst could be used 4 times without any significant loss of activity.
KW - 2,5-Diformylfuran (DFF)
KW - 5-Hydroxymethyl-2-furfural (HMF)
KW - Extracting solvent
KW - Methyl isobutyl ketone (MIBK)
KW - Oxidation
KW - Vanadium
UR - http://www.scopus.com/inward/record.url?scp=84906655748&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84906655748&partnerID=8YFLogxK
U2 - 10.1016/j.catcom.2014.08.008
DO - 10.1016/j.catcom.2014.08.008
M3 - Article
AN - SCOPUS:84906655748
VL - 57
SP - 64
EP - 68
JO - Catalysis Communications
JF - Catalysis Communications
SN - 1566-7367
ER -