Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran catalyzed by vanadium supported activated carbon in MIBK, extracting solvent for HMF

Churchil A. Antonyraj, Bora Kim, Yongjin Kim, Seunghan Shin, Kwan Young Lee, Il Kim, Jin Ku Cho

Research output: Contribution to journalArticle

44 Citations (Scopus)

Abstract

Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using molecular oxygen and vanadium catalyst onto activated carbon in MIBK, extracting solvent for HMF, is described. Highly stable V2O5 supported on activated carbon catalyst was synthesized using V3 + (VCl3) precursor and confirmed by XPS analysis, which found to be highly active. A maximum HMF conversion of > 95% with > 96% DFF selectivity was achieved and this heterogeneous catalyst could be used 4 times without any significant loss of activity.

Original languageEnglish
Pages (from-to)64-68
Number of pages5
JournalCatalysis Communications
Volume57
DOIs
Publication statusPublished - 2014 Dec 5

Fingerprint

Furfural
Vanadium
Activated carbon
Oxidation
Catalysts
Molecular oxygen
Catalyst selectivity
X ray photoelectron spectroscopy
2,5-diformylfuran
5-hydroxymethylfurfural

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology
  • Chemistry(all)

Cite this

Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran catalyzed by vanadium supported activated carbon in MIBK, extracting solvent for HMF. / Antonyraj, Churchil A.; Kim, Bora; Kim, Yongjin; Shin, Seunghan; Lee, Kwan Young; Kim, Il; Cho, Jin Ku.

In: Catalysis Communications, Vol. 57, 05.12.2014, p. 64-68.

Research output: Contribution to journalArticle

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abstract = "Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using molecular oxygen and vanadium catalyst onto activated carbon in MIBK, extracting solvent for HMF, is described. Highly stable V2O5 supported on activated carbon catalyst was synthesized using V3 + (VCl3) precursor and confirmed by XPS analysis, which found to be highly active. A maximum HMF conversion of > 95{\%} with > 96{\%} DFF selectivity was achieved and this heterogeneous catalyst could be used 4 times without any significant loss of activity.",
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AU - Kim, Bora

AU - Kim, Yongjin

AU - Shin, Seunghan

AU - Lee, Kwan Young

AU - Kim, Il

AU - Cho, Jin Ku

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AB - Heterogeneous selective oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-diformylfuran (DFF) using molecular oxygen and vanadium catalyst onto activated carbon in MIBK, extracting solvent for HMF, is described. Highly stable V2O5 supported on activated carbon catalyst was synthesized using V3 + (VCl3) precursor and confirmed by XPS analysis, which found to be highly active. A maximum HMF conversion of > 95% with > 96% DFF selectivity was achieved and this heterogeneous catalyst could be used 4 times without any significant loss of activity.

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