Hierarchical cobalt-nitride and -oxide co-doped porous carbon nanostructures for highly efficient and durable bifunctional oxygen reaction electrocatalysts

Kyung Jin Lee, Dong Yun Shin, Ayeong Byeon, Ahyoun Lim, Young Suk Jo, Alina Begley, Dong Hee Lim, Yung Eun Sung, Hyun S. Park, Keun Hwa Chae, SukWoo Nam, Kwan Young Lee, Jin Young Kim

Research output: Contribution to journalArticle

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Abstract

Here we report the preparation of hollow microspheres with a thin shell composed of mixed cobalt nitride (Co-N) and cobalt oxide (Co-O) nanofragments encapsulated in thin layers of nitrogen-doped carbon (N-C) nanostructure (Co-N/Co-O@N-C) arrays with enhanced bifunctional oxygen electrochemical performance. The hybrid structures are synthesized via heat treatment of N-doped hollow carbon microspheres with cobalt nitrate, and both the specific ratio of these precursors and the selected annealing temperature are found to be the key factors for the formation of the unique hybrid structure. The as-obtained product (Co-N/Co-O@N-C) presents a large specific surface area (493 m2 g-1), high-level heteroatom doping (Co-N, Co-O, and N-C), and hierarchical porous nanoarchitecture containing macroporous frameworks and mesoporous walls. Electronic interaction between the thin N-C layers and the encapsulated Co-N and Co-O nanofragments efficiently optimizes oxygen adsorption properties on the Co-N/Co-O@N-C and thereby triggers bifunctional oxygen electrochemical activity at the surface. The Co-N/Co-O@N-C nanohybrid exhibited a high onset potential of 0.93 V, and a limiting current density of 5.6 mA cm-2 indicating 4-electron oxygen reduction reaction (ORR), afforded high catalytic activity for the oxygen evolution reaction (OER) and even exceeded the catalytic stability of the commercial precious electrocatalysts; furthermore, when integrated into the oxygen electrode of a regenerative fuel cell device, it exhibited high-performance oxygen electrodes for both the ORR and the OER.

Original languageEnglish
Pages (from-to)15846-15855
Number of pages10
JournalNanoscale
Volume9
Issue number41
DOIs
Publication statusPublished - 2017 Nov 1

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Electrocatalysts
Cobalt
Nitrides
Oxides
Nanostructures
Carbon
Oxygen
Nitrogen
Nitrogen oxides
Microspheres
Regenerative fuel cells
Electrodes
cobalt oxide
Specific surface area
Catalyst activity
Current density
Heat treatment
Doping (additives)
Annealing
Adsorption

ASJC Scopus subject areas

  • Materials Science(all)

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Hierarchical cobalt-nitride and -oxide co-doped porous carbon nanostructures for highly efficient and durable bifunctional oxygen reaction electrocatalysts. / Lee, Kyung Jin; Shin, Dong Yun; Byeon, Ayeong; Lim, Ahyoun; Jo, Young Suk; Begley, Alina; Lim, Dong Hee; Sung, Yung Eun; Park, Hyun S.; Chae, Keun Hwa; Nam, SukWoo; Lee, Kwan Young; Kim, Jin Young.

In: Nanoscale, Vol. 9, No. 41, 01.11.2017, p. 15846-15855.

Research output: Contribution to journalArticle

Lee, KJ, Shin, DY, Byeon, A, Lim, A, Jo, YS, Begley, A, Lim, DH, Sung, YE, Park, HS, Chae, KH, Nam, S, Lee, KY & Kim, JY 2017, 'Hierarchical cobalt-nitride and -oxide co-doped porous carbon nanostructures for highly efficient and durable bifunctional oxygen reaction electrocatalysts', Nanoscale, vol. 9, no. 41, pp. 15846-15855. https://doi.org/10.1039/c7nr06646e
Lee, Kyung Jin ; Shin, Dong Yun ; Byeon, Ayeong ; Lim, Ahyoun ; Jo, Young Suk ; Begley, Alina ; Lim, Dong Hee ; Sung, Yung Eun ; Park, Hyun S. ; Chae, Keun Hwa ; Nam, SukWoo ; Lee, Kwan Young ; Kim, Jin Young. / Hierarchical cobalt-nitride and -oxide co-doped porous carbon nanostructures for highly efficient and durable bifunctional oxygen reaction electrocatalysts. In: Nanoscale. 2017 ; Vol. 9, No. 41. pp. 15846-15855.
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T1 - Hierarchical cobalt-nitride and -oxide co-doped porous carbon nanostructures for highly efficient and durable bifunctional oxygen reaction electrocatalysts

AU - Lee, Kyung Jin

AU - Shin, Dong Yun

AU - Byeon, Ayeong

AU - Lim, Ahyoun

AU - Jo, Young Suk

AU - Begley, Alina

AU - Lim, Dong Hee

AU - Sung, Yung Eun

AU - Park, Hyun S.

AU - Chae, Keun Hwa

AU - Nam, SukWoo

AU - Lee, Kwan Young

AU - Kim, Jin Young

PY - 2017/11/1

Y1 - 2017/11/1

N2 - Here we report the preparation of hollow microspheres with a thin shell composed of mixed cobalt nitride (Co-N) and cobalt oxide (Co-O) nanofragments encapsulated in thin layers of nitrogen-doped carbon (N-C) nanostructure (Co-N/Co-O@N-C) arrays with enhanced bifunctional oxygen electrochemical performance. The hybrid structures are synthesized via heat treatment of N-doped hollow carbon microspheres with cobalt nitrate, and both the specific ratio of these precursors and the selected annealing temperature are found to be the key factors for the formation of the unique hybrid structure. The as-obtained product (Co-N/Co-O@N-C) presents a large specific surface area (493 m2 g-1), high-level heteroatom doping (Co-N, Co-O, and N-C), and hierarchical porous nanoarchitecture containing macroporous frameworks and mesoporous walls. Electronic interaction between the thin N-C layers and the encapsulated Co-N and Co-O nanofragments efficiently optimizes oxygen adsorption properties on the Co-N/Co-O@N-C and thereby triggers bifunctional oxygen electrochemical activity at the surface. The Co-N/Co-O@N-C nanohybrid exhibited a high onset potential of 0.93 V, and a limiting current density of 5.6 mA cm-2 indicating 4-electron oxygen reduction reaction (ORR), afforded high catalytic activity for the oxygen evolution reaction (OER) and even exceeded the catalytic stability of the commercial precious electrocatalysts; furthermore, when integrated into the oxygen electrode of a regenerative fuel cell device, it exhibited high-performance oxygen electrodes for both the ORR and the OER.

AB - Here we report the preparation of hollow microspheres with a thin shell composed of mixed cobalt nitride (Co-N) and cobalt oxide (Co-O) nanofragments encapsulated in thin layers of nitrogen-doped carbon (N-C) nanostructure (Co-N/Co-O@N-C) arrays with enhanced bifunctional oxygen electrochemical performance. The hybrid structures are synthesized via heat treatment of N-doped hollow carbon microspheres with cobalt nitrate, and both the specific ratio of these precursors and the selected annealing temperature are found to be the key factors for the formation of the unique hybrid structure. The as-obtained product (Co-N/Co-O@N-C) presents a large specific surface area (493 m2 g-1), high-level heteroatom doping (Co-N, Co-O, and N-C), and hierarchical porous nanoarchitecture containing macroporous frameworks and mesoporous walls. Electronic interaction between the thin N-C layers and the encapsulated Co-N and Co-O nanofragments efficiently optimizes oxygen adsorption properties on the Co-N/Co-O@N-C and thereby triggers bifunctional oxygen electrochemical activity at the surface. The Co-N/Co-O@N-C nanohybrid exhibited a high onset potential of 0.93 V, and a limiting current density of 5.6 mA cm-2 indicating 4-electron oxygen reduction reaction (ORR), afforded high catalytic activity for the oxygen evolution reaction (OER) and even exceeded the catalytic stability of the commercial precious electrocatalysts; furthermore, when integrated into the oxygen electrode of a regenerative fuel cell device, it exhibited high-performance oxygen electrodes for both the ORR and the OER.

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