Hierarchical Zn                         1.67                         Mn                         1.33                         O                         4                         /graphene nanoaggregates as new anode material for lithium-ion batteries

Jae Wan Lee; Seung Deok Seo; Dong Wan Kim

doi:10.1002/er.4381

Hierarchical Zn _1.67 Mn _1.33 O ₄ /graphene nanoaggregates as new anode material for lithium-ion batteries

Jae Wan Lee, Seung Deok Seo, Dong Wan Kim

School of Civil, Environmental and Architectural Engineering

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Cubic spinel type Zn _1.67 Mn _1.33 O ₄ porous sub-micro spheres were synthesized by the calcination of solvothermally prepared Zn _x Mn _1 − x CO ₃ precursor powders and evaluated as new anode materials for Li-ion batteries for the first time. Each sphere exhibited aggregated morphology, constructed entirely from nanoparticles with a primary particle size of 11 nm. Electrochemical investigations and ex-situ transmission electron microscopy analyses revealed that the reaction mechanism of obtained Zn _1.67 Mn _1.33 O ₄ nanoaggregates is the combined conversion and alloying reaction, similar to that of ZnMn ₂ O ₄ systems. In favor of the uniform porous sphere structure, these resulting Zn _1.67 Mn _1.33 O ₄ nanoaggregates enabled the mitigation of volume change upon cycling. In addition, graphene composites with Zn _1.67 Mn _1.33 O ₄ nanoaggregates were fabricated to improve electrical conductivity, simply by adding graphenes during solvothermal reaction for the formation of Zn _x Mn _1 − x CO ₃ precursors. Zn _1.67 Mn _1.33 O ₄ /graphene composites showed a capacity of 670 mA h g ⁻¹ higher than that of pure Zn _1.67 Mn _1.33 O ₄ (518 mA h g ⁻¹ ) after 200 cycle at a current density of 100 mA g ⁻¹ .

Original language	English
Pages (from-to)	1735-1746
Number of pages	12
Journal	International Journal of Energy Research
Volume	43
Issue number	5
DOIs	https://doi.org/10.1002/er.4381
Publication status	Published - 2019 Apr

Keywords

Zn Mn O /graphene
cubic spinel structure anode
lithium-ion batteries
nanoaggregates
transition metal oxide

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Nuclear Energy and Engineering
Fuel Technology
Energy Engineering and Power Technology

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/er.4381

Cite this

Lee, J. W., Seo, S. D., & Kim, D. W. (2019). Hierarchical Zn _1.67 Mn _1.33 O ₄ /graphene nanoaggregates as new anode material for lithium-ion batteries International Journal of Energy Research, 43(5), 1735-1746. https://doi.org/10.1002/er.4381

Hierarchical Zn _1.67 Mn _1.33 O ₄ /graphene nanoaggregates as new anode material for lithium-ion batteries . / Lee, Jae Wan; Seo, Seung Deok; Kim, Dong Wan.

In: International Journal of Energy Research, Vol. 43, No. 5, 04.2019, p. 1735-1746.

Research output: Contribution to journal › Article › peer-review

Lee, JW, Seo, SD & Kim, DW 2019, ' Hierarchical Zn _1.67 Mn _1.33 O ₄ /graphene nanoaggregates as new anode material for lithium-ion batteries ', International Journal of Energy Research, vol. 43, no. 5, pp. 1735-1746. https://doi.org/10.1002/er.4381

Lee JW, Seo SD, Kim DW. Hierarchical Zn _1.67 Mn _1.33 O ₄ /graphene nanoaggregates as new anode material for lithium-ion batteries International Journal of Energy Research. 2019 Apr;43(5):1735-1746. https://doi.org/10.1002/er.4381

Lee, Jae Wan ; Seo, Seung Deok ; Kim, Dong Wan. / Hierarchical Zn _1.67 Mn _1.33 O ₄ /graphene nanoaggregates as new anode material for lithium-ion batteries In: International Journal of Energy Research. 2019 ; Vol. 43, No. 5. pp. 1735-1746.

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title = " Hierarchical Zn 1.67 Mn 1.33 O 4 /graphene nanoaggregates as new anode material for lithium-ion batteries ",

abstract = " Cubic spinel type Zn 1.67 Mn 1.33 O 4 porous sub-micro spheres were synthesized by the calcination of solvothermally prepared Zn x Mn 1 − x CO 3 precursor powders and evaluated as new anode materials for Li-ion batteries for the first time. Each sphere exhibited aggregated morphology, constructed entirely from nanoparticles with a primary particle size of 11 nm. Electrochemical investigations and ex-situ transmission electron microscopy analyses revealed that the reaction mechanism of obtained Zn 1.67 Mn 1.33 O 4 nanoaggregates is the combined conversion and alloying reaction, similar to that of ZnMn 2 O 4 systems. In favor of the uniform porous sphere structure, these resulting Zn 1.67 Mn 1.33 O 4 nanoaggregates enabled the mitigation of volume change upon cycling. In addition, graphene composites with Zn 1.67 Mn 1.33 O 4 nanoaggregates were fabricated to improve electrical conductivity, simply by adding graphenes during solvothermal reaction for the formation of Zn x Mn 1 − x CO 3 precursors. Zn 1.67 Mn 1.33 O 4 /graphene composites showed a capacity of 670 mA h g −1 higher than that of pure Zn 1.67 Mn 1.33 O 4 (518 mA h g −1 ) after 200 cycle at a current density of 100 mA g −1 . ",

keywords = "Zn Mn O /graphene, cubic spinel structure anode, lithium-ion batteries, nanoaggregates, transition metal oxide",

author = "Lee, {Jae Wan} and Seo, {Seung Deok} and Kim, {Dong Wan}",

note = "Funding Information: This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science, ICT, and Future Planning, South Korea (No. 2018M3D1A1058744) and by the R&D Center for Valuable Recycling (Global-Top R&BD Program) of the Ministry of Environment, South Korea (Project No.: 2016002250005). We thank the Korea Basic Science Institute, South Korea for the technical support. Funding Information: This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science, ICT, and Future Planning, South Korea (No. 2018M3D1A1058744) and by the R&D Center for Valuable Recycling (Global‐Top R&BD Program) of the Ministry of Environment, South Korea (Project No.: 2016002250005). Funding Information: R&D Center for Valuable Recycling (Global‐Top R&BD Program) of the Min istry of Environment, South Korea, Grant/ Award Number: 2016002250005; Ministry of Science, ICT, and Future Planning, South Korea, Grant/Award Number: 2018M3D1A1058744; National Research Foundation of Korea (NRF)",

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AU - Lee, Jae Wan

AU - Seo, Seung Deok

AU - Kim, Dong Wan

N1 - Funding Information: This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science, ICT, and Future Planning, South Korea (No. 2018M3D1A1058744) and by the R&D Center for Valuable Recycling (Global-Top R&BD Program) of the Ministry of Environment, South Korea (Project No.: 2016002250005). We thank the Korea Basic Science Institute, South Korea for the technical support. Funding Information: This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science, ICT, and Future Planning, South Korea (No. 2018M3D1A1058744) and by the R&D Center for Valuable Recycling (Global‐Top R&BD Program) of the Ministry of Environment, South Korea (Project No.: 2016002250005). Funding Information: R&D Center for Valuable Recycling (Global‐Top R&BD Program) of the Min istry of Environment, South Korea, Grant/ Award Number: 2016002250005; Ministry of Science, ICT, and Future Planning, South Korea, Grant/Award Number: 2018M3D1A1058744; National Research Foundation of Korea (NRF)

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N2 - Cubic spinel type Zn 1.67 Mn 1.33 O 4 porous sub-micro spheres were synthesized by the calcination of solvothermally prepared Zn x Mn 1 − x CO 3 precursor powders and evaluated as new anode materials for Li-ion batteries for the first time. Each sphere exhibited aggregated morphology, constructed entirely from nanoparticles with a primary particle size of 11 nm. Electrochemical investigations and ex-situ transmission electron microscopy analyses revealed that the reaction mechanism of obtained Zn 1.67 Mn 1.33 O 4 nanoaggregates is the combined conversion and alloying reaction, similar to that of ZnMn 2 O 4 systems. In favor of the uniform porous sphere structure, these resulting Zn 1.67 Mn 1.33 O 4 nanoaggregates enabled the mitigation of volume change upon cycling. In addition, graphene composites with Zn 1.67 Mn 1.33 O 4 nanoaggregates were fabricated to improve electrical conductivity, simply by adding graphenes during solvothermal reaction for the formation of Zn x Mn 1 − x CO 3 precursors. Zn 1.67 Mn 1.33 O 4 /graphene composites showed a capacity of 670 mA h g −1 higher than that of pure Zn 1.67 Mn 1.33 O 4 (518 mA h g −1 ) after 200 cycle at a current density of 100 mA g −1 .

AB - Cubic spinel type Zn 1.67 Mn 1.33 O 4 porous sub-micro spheres were synthesized by the calcination of solvothermally prepared Zn x Mn 1 − x CO 3 precursor powders and evaluated as new anode materials for Li-ion batteries for the first time. Each sphere exhibited aggregated morphology, constructed entirely from nanoparticles with a primary particle size of 11 nm. Electrochemical investigations and ex-situ transmission electron microscopy analyses revealed that the reaction mechanism of obtained Zn 1.67 Mn 1.33 O 4 nanoaggregates is the combined conversion and alloying reaction, similar to that of ZnMn 2 O 4 systems. In favor of the uniform porous sphere structure, these resulting Zn 1.67 Mn 1.33 O 4 nanoaggregates enabled the mitigation of volume change upon cycling. In addition, graphene composites with Zn 1.67 Mn 1.33 O 4 nanoaggregates were fabricated to improve electrical conductivity, simply by adding graphenes during solvothermal reaction for the formation of Zn x Mn 1 − x CO 3 precursors. Zn 1.67 Mn 1.33 O 4 /graphene composites showed a capacity of 670 mA h g −1 higher than that of pure Zn 1.67 Mn 1.33 O 4 (518 mA h g −1 ) after 200 cycle at a current density of 100 mA g −1 .

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