High-pressure phase behaviour of poly(d-lactic acid), trichloromethane, and carbon dioxide ternary mixture systems

Taehyun Im; Jung Min Gwon; Soo Hyun Kim; Hun Yong Shin; Hwayong Kim

doi:10.1016/j.jct.2015.06.033

High-pressure phase behaviour of poly(d-lactic acid), trichloromethane, and carbon dioxide ternary mixture systems

Taehyun Im, Jung Min Gwon, Soo Hyun Kim, Hun Yong Shin, Hwayong Kim

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Abstract The high pressure phase behaviour of poly(d-lactic acid) (M_w = 359,000), trichloromethane, and carbon dioxide ternary mixture systems is presented in this study. Cloud and bubble point pressures were measured using a variable volume view cell at temperatures (313.15 to 363.15) K and pressures up to 33.6 MPa. The hybrid equation of state for the polymer-carbon dioxide system was used to correlate the experimental results. The van der Waals one-fluid mixing rule with three adjustable binary interaction parameters was used for all correlations. The binary parameters were optimised using the simplex method algorithm.

Original language	English
Article number	4292
Pages (from-to)	216-223
Number of pages	8
Journal	Journal of Chemical Thermodynamics
Volume	90
DOIs	https://doi.org/10.1016/j.jct.2015.06.033
Publication status	Published - 2015 Jul 22
Externally published	Yes

Keywords

(Polymer + solvent + gas) ternary systems
Biodegradable polymer
Poly(d-lactic acid)
Supercritical carbon dioxide
The hybrid equation of state for (CO<inf>2</inf> + polymer) system

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Materials Science(all)
Physical and Theoretical Chemistry

Access to Document

10.1016/j.jct.2015.06.033

Cite this

@article{ea9371f368e44c11a073018f52fbe0a5,

title = "High-pressure phase behaviour of poly(d-lactic acid), trichloromethane, and carbon dioxide ternary mixture systems",

abstract = "Abstract The high pressure phase behaviour of poly(d-lactic acid) (Mw = 359,000), trichloromethane, and carbon dioxide ternary mixture systems is presented in this study. Cloud and bubble point pressures were measured using a variable volume view cell at temperatures (313.15 to 363.15) K and pressures up to 33.6 MPa. The hybrid equation of state for the polymer-carbon dioxide system was used to correlate the experimental results. The van der Waals one-fluid mixing rule with three adjustable binary interaction parameters was used for all correlations. The binary parameters were optimised using the simplex method algorithm.",

keywords = "(Polymer + solvent + gas) ternary systems, Biodegradable polymer, Poly(d-lactic acid), Supercritical carbon dioxide, The hybrid equation of state for (CO<inf>2</inf> + polymer) system",

author = "Taehyun Im and Gwon, {Jung Min} and Kim, {Soo Hyun} and Shin, {Hun Yong} and Hwayong Kim",

note = "Funding Information: This work was supported by the Korea government (MEST) ( NRF-2012M1A2A2671789 ). Publisher Copyright: {\textcopyright} 2015 Published by Elsevier Ltd.",

year = "2015",

month = jul,

day = "22",

doi = "10.1016/j.jct.2015.06.033",

language = "English",

volume = "90",

pages = "216--223",

journal = "Journal of Chemical Thermodynamics",

issn = "0021-9614",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - High-pressure phase behaviour of poly(d-lactic acid), trichloromethane, and carbon dioxide ternary mixture systems

AU - Im, Taehyun

AU - Gwon, Jung Min

AU - Kim, Soo Hyun

AU - Shin, Hun Yong

AU - Kim, Hwayong

PY - 2015/7/22

Y1 - 2015/7/22

N2 - Abstract The high pressure phase behaviour of poly(d-lactic acid) (Mw = 359,000), trichloromethane, and carbon dioxide ternary mixture systems is presented in this study. Cloud and bubble point pressures were measured using a variable volume view cell at temperatures (313.15 to 363.15) K and pressures up to 33.6 MPa. The hybrid equation of state for the polymer-carbon dioxide system was used to correlate the experimental results. The van der Waals one-fluid mixing rule with three adjustable binary interaction parameters was used for all correlations. The binary parameters were optimised using the simplex method algorithm.

AB - Abstract The high pressure phase behaviour of poly(d-lactic acid) (Mw = 359,000), trichloromethane, and carbon dioxide ternary mixture systems is presented in this study. Cloud and bubble point pressures were measured using a variable volume view cell at temperatures (313.15 to 363.15) K and pressures up to 33.6 MPa. The hybrid equation of state for the polymer-carbon dioxide system was used to correlate the experimental results. The van der Waals one-fluid mixing rule with three adjustable binary interaction parameters was used for all correlations. The binary parameters were optimised using the simplex method algorithm.

KW - (Polymer + solvent + gas) ternary systems

KW - Biodegradable polymer

KW - Poly(d-lactic acid)

KW - Supercritical carbon dioxide

KW - The hybrid equation of state for (CO<inf>2</inf> + polymer) system

UR - http://www.scopus.com/inward/record.url?scp=84937579951&partnerID=8YFLogxK

U2 - 10.1016/j.jct.2015.06.033

DO - 10.1016/j.jct.2015.06.033

M3 - Article

AN - SCOPUS:84937579951

SN - 0021-9614

VL - 90

SP - 216

EP - 223

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

M1 - 4292

ER -

High-pressure phase behaviour of poly(d-lactic acid), trichloromethane, and carbon dioxide ternary mixture systems

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this