Highly dispersed ruthenium nanoparticle-embedded mesoporous silica as a catalyst for the production of γ-butyrolactone from succinic anhydride

Sang Ho Chung, Hee Jun Eom, Min Sung Kim, Myung Suk Lee, Kwan Young Lee

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In this study, a novel, strategic method was developed for the synthesis of a mesoporous silica catalyst embedded with ruthenium nanoparticles (RuNPs/SiO2) by combining the polyol and modified sol-gel methods. By applying this new procedure, uniformly synthesized ruthenium nanoparticles with an average size of 3.8 nm and 95% spherical shape were highly dispersed in the mesoporous silica support material. Coordinated carbonyl groups of PVP remaining from the synthesis of the RuNPs were effectively removed by the thermal treatment (calcined at 573 K for 4 h) and the sythesized RuNPs/SiO2 catalysts were reduced under hydrogen at 20 bar for 2 h. These catalysts were analyzed using transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), N2 adsorption-desorption, and X-ray diffraction (XRD). After the thermal treatment and the reduction procedure, the size and shape of the embedded RuNPs were nearly unchanged, and the catalyst was active in the liquid-phase hydrogenation of succinic anhydride (SAN) to selectively form γ-butyrolactone (GBL) with a maximum yield of 90.1%. This novel catalyst preparation is a potentially useful method for the synthesis of metal nanoparticles as heterogeneous catalysts.

Original languageEnglish
Pages (from-to)7701-7706
Number of pages6
JournalJournal of Nanoscience and Nanotechnology
Volume13
Issue number11
DOIs
Publication statusPublished - 2013 Nov 1

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Ruthenium
anhydrides
Silicon Dioxide
Nanoparticles
ruthenium
Silica
silicon dioxide
catalysts
nanoparticles
Catalysts
Hot Temperature
Metal Nanoparticles
synthesis
Heat treatment
Hydrogenation
Polymethyl Methacrylate
Fourier Transform Infrared Spectroscopy
Transmission Electron Microscopy
X-Ray Diffraction
Metal nanoparticles

Keywords

  • Hydrogenation
  • Ruthenium nanoparticle-embedded catalysts
  • Succinic anhydride

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Chemistry(all)
  • Materials Science(all)
  • Bioengineering
  • Biomedical Engineering

Cite this

Highly dispersed ruthenium nanoparticle-embedded mesoporous silica as a catalyst for the production of γ-butyrolactone from succinic anhydride. / Chung, Sang Ho; Eom, Hee Jun; Kim, Min Sung; Lee, Myung Suk; Lee, Kwan Young.

In: Journal of Nanoscience and Nanotechnology, Vol. 13, No. 11, 01.11.2013, p. 7701-7706.

Research output: Contribution to journalArticle

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