Highly Selective Xylene Sensor Based on NiO/NiMoO4 Nanocomposite Hierarchical Spheres for Indoor Air Monitoring

Bo Young Kim, Jee Hyun Ahn, Ji Wook Yoon, Chul Soon Lee, Yun Chan Kang, Faissal Abdel-Hady, Abdulaziz A. Wazzan, Jong Heun Lee

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

Xylene is a hazardous volatile organic compound, which should be measured precisely for monitoring of indoor air quality. The selective detection of ppm-level xylene using oxide semiconductor chemiresistors, however, remains a challenging issue. In this study, NiO/NiMoO4 nanocomposite hierarchical spheres assembled from nanosheets were prepared by hydrothermal reaction, and the potential of sensors composed of these nanocomposites to selectively detect xylene gas was investigated. The sensors based on the NiO/NiMoO4 nanocomposite hierarchical spheres exhibited high responses (maximum resistance ratio =101.5) to 5 ppm p-xylene with low cross-responses (resistance ratios <30) to 5 ppm toluene, benzene, C2H5OH, CH3COCH3, HCHO, CO, trimethylamine, and NH3. In contrast, a sensor based on pure NiO hierarchical spheres exhibited negligibly low responses to all 9 analyte gases. The gas-sensing mechanism underlying the high selectivity and response to xylene in the NiO/NiMoO4 nanocomposite hierarchical spheres is discussed in relation to the catalytic promotion of the xylene-sensing reaction by synergistic combination between NiO and NiMoO4, gas-accessible hierarchical morphology, and electronic sensitization by Mo addition. Highly selective detection of xylene can pave the road toward a new solution for precise monitoring of indoor air pollution.

Original languageEnglish
Pages (from-to)34603-34611
Number of pages9
JournalACS Applied Materials and Interfaces
Volume8
Issue number50
DOIs
Publication statusPublished - 2016 Dec 21

Fingerprint

Xylenes
Xylene
Nanocomposites
Monitoring
Sensors
Air
Gases
Indoor air pollution
Volatile Organic Compounds
Nanosheets
Toluene
Carbon Monoxide
Benzene
Air quality
Volatile organic compounds

Keywords

  • hierarchical structures
  • NiMoO
  • NiO
  • selective gas sensor
  • xylene

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Highly Selective Xylene Sensor Based on NiO/NiMoO4 Nanocomposite Hierarchical Spheres for Indoor Air Monitoring. / Kim, Bo Young; Ahn, Jee Hyun; Yoon, Ji Wook; Lee, Chul Soon; Kang, Yun Chan; Abdel-Hady, Faissal; Wazzan, Abdulaziz A.; Lee, Jong Heun.

In: ACS Applied Materials and Interfaces, Vol. 8, No. 50, 21.12.2016, p. 34603-34611.

Research output: Contribution to journalArticle

Kim, Bo Young ; Ahn, Jee Hyun ; Yoon, Ji Wook ; Lee, Chul Soon ; Kang, Yun Chan ; Abdel-Hady, Faissal ; Wazzan, Abdulaziz A. ; Lee, Jong Heun. / Highly Selective Xylene Sensor Based on NiO/NiMoO4 Nanocomposite Hierarchical Spheres for Indoor Air Monitoring. In: ACS Applied Materials and Interfaces. 2016 ; Vol. 8, No. 50. pp. 34603-34611.
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