Highly stable tandem solar cell monolithically integrating dye-sensitized and CIGS solar cells

Sang Youn Chae, Se Jin Park, Oh Shim Joo, Yongseok Jun, Byoung Koun Min, Yun Jeong Hwang

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A highly stable monolithic tandem solar cell was developed by combining the heterogeneous photovoltaic technologies of dye-sensitized solar cell (DSSC) and solution-processed CuInx Ga1-x Sey S1-y (CIGS) thin film solar cells. The durability of the tandem cell was dramatically enhanced by replacing the redox couple from to [Co(bpy)3]2+/[Co(bpy)3]3+), accompanied by a well-matched counter electrode (PEDOT:PSS) and sensitizer (Y123). A 1000 h durability test of the DSSC/CIGS tandem solar cell in ambient conditions resulted in only a 5% decrease in solar cell efficiency. Based on electrochemical impedance spectroscopy and photoelectrochemical cell measurement, the enhanced stability of the tandem cell is attributed to minimal corrosion by the cobalt-based polypyridine complex redox couple.

Original languageEnglish
Article number30868
JournalScientific Reports
Publication statusPublished - 2016 Aug 4


ASJC Scopus subject areas

  • General

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