ICT-based Cu(II)-sensing 9,10-anthraquinonecalix[4]crown

Hyun Jung Kim, Sang Hoon Kim, Ja Hyung Kim, Le Ngoc Anh, Joung Hae Lee, Chang Hee Lee, Jong Seung Kim

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

A series of calix[4]arene-based chromogenic sensors bearing the 9,10-anthraquinone moiety have been synthesized and examined for their abilities to recognize various cations such as Li+, Na+, K+, Rb+, Cs+, Ag+, Cd2+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Hg2+, Pb2+, Co2+, and Cu2+ by UV-vis spectroscopy. In acetonitrile, the presence of Cu2+ induces the formation of the 1:1 ligand/metal complex, which exhibits a new absorption band centered at 450 nm, and leads to an obvious color change from yellow to red.

Original languageEnglish
Pages (from-to)2782-2786
Number of pages5
JournalTetrahedron Letters
Volume50
Issue number23
DOIs
Publication statusPublished - 2009 Jun 10

Keywords

  • Anthraquinone
  • Calixarenes
  • Chromogenic
  • Copper ion
  • ICT

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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    Kim, H. J., Kim, S. H., Kim, J. H., Anh, L. N., Lee, J. H., Lee, C. H., & Kim, J. S. (2009). ICT-based Cu(II)-sensing 9,10-anthraquinonecalix[4]crown. Tetrahedron Letters, 50(23), 2782-2786. https://doi.org/10.1016/j.tetlet.2009.03.149