ICT-based Cu(II)-sensing 9,10-anthraquinonecalix[4]crown

Hyun Jung Kim; Sang Hoon Kim; Ja Hyung Kim; Le Ngoc Anh; Joung Hae Lee; Chang Hee Lee; Jong Seung Kim

doi:10.1016/j.tetlet.2009.03.149

ICT-based Cu(II)-sensing 9,10-anthraquinonecalix[4]crown

Hyun Jung Kim, Sang Hoon Kim, Ja Hyung Kim, Le Ngoc Anh, Joung Hae Lee, Chang Hee Lee, Jong Seung Kim

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

A series of calix[4]arene-based chromogenic sensors bearing the 9,10-anthraquinone moiety have been synthesized and examined for their abilities to recognize various cations such as Li⁺, Na⁺, K⁺, Rb⁺, Cs⁺, Ag⁺, Cd²⁺, Mg²⁺, Ca²⁺, Sr²⁺, Ba²⁺, Zn²⁺, Hg²⁺, Pb²⁺, Co²⁺, and Cu²⁺ by UV-vis spectroscopy. In acetonitrile, the presence of Cu²⁺ induces the formation of the 1:1 ligand/metal complex, which exhibits a new absorption band centered at 450 nm, and leads to an obvious color change from yellow to red.

Original language	English
Pages (from-to)	2782-2786
Number of pages	5
Journal	Tetrahedron Letters
Volume	50
Issue number	23
DOIs	https://doi.org/10.1016/j.tetlet.2009.03.149
Publication status	Published - 2009 Jun 10

Keywords

Anthraquinone
Calixarenes
Chromogenic
Copper ion
ICT

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/j.tetlet.2009.03.149

Cite this

@article{391d07d868c149a58af83e5bf2695807,

title = "ICT-based Cu(II)-sensing 9,10-anthraquinonecalix[4]crown",

abstract = "A series of calix[4]arene-based chromogenic sensors bearing the 9,10-anthraquinone moiety have been synthesized and examined for their abilities to recognize various cations such as Li+, Na+, K+, Rb+, Cs+, Ag+, Cd2+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Hg2+, Pb2+, Co2+, and Cu2+ by UV-vis spectroscopy. In acetonitrile, the presence of Cu2+ induces the formation of the 1:1 ligand/metal complex, which exhibits a new absorption band centered at 450 nm, and leads to an obvious color change from yellow to red.",

keywords = "Anthraquinone, Calixarenes, Chromogenic, Copper ion, ICT",

author = "Kim, {Hyun Jung} and Kim, {Sang Hoon} and Kim, {Ja Hyung} and Anh, {Le Ngoc} and Lee, {Joung Hae} and Lee, {Chang Hee} and Kim, {Jong Seung}",

note = "Funding Information: This work was supported by the KOSEF Grants (R11-2005-008-00000-0 and R01-2006-000-10001-0), KRISS Grant (R0900641), and KRF Grant (C00426). ",

year = "2009",

month = jun,

day = "10",

doi = "10.1016/j.tetlet.2009.03.149",

language = "English",

volume = "50",

pages = "2782--2786",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "23",

}

TY - JOUR

T1 - ICT-based Cu(II)-sensing 9,10-anthraquinonecalix[4]crown

AU - Kim, Hyun Jung

AU - Kim, Sang Hoon

AU - Kim, Ja Hyung

AU - Anh, Le Ngoc

AU - Lee, Joung Hae

AU - Lee, Chang Hee

AU - Kim, Jong Seung

N1 - Funding Information: This work was supported by the KOSEF Grants (R11-2005-008-00000-0 and R01-2006-000-10001-0), KRISS Grant (R0900641), and KRF Grant (C00426).

PY - 2009/6/10

Y1 - 2009/6/10

N2 - A series of calix[4]arene-based chromogenic sensors bearing the 9,10-anthraquinone moiety have been synthesized and examined for their abilities to recognize various cations such as Li+, Na+, K+, Rb+, Cs+, Ag+, Cd2+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Hg2+, Pb2+, Co2+, and Cu2+ by UV-vis spectroscopy. In acetonitrile, the presence of Cu2+ induces the formation of the 1:1 ligand/metal complex, which exhibits a new absorption band centered at 450 nm, and leads to an obvious color change from yellow to red.

AB - A series of calix[4]arene-based chromogenic sensors bearing the 9,10-anthraquinone moiety have been synthesized and examined for their abilities to recognize various cations such as Li+, Na+, K+, Rb+, Cs+, Ag+, Cd2+, Mg2+, Ca2+, Sr2+, Ba2+, Zn2+, Hg2+, Pb2+, Co2+, and Cu2+ by UV-vis spectroscopy. In acetonitrile, the presence of Cu2+ induces the formation of the 1:1 ligand/metal complex, which exhibits a new absorption band centered at 450 nm, and leads to an obvious color change from yellow to red.

KW - Anthraquinone

KW - Calixarenes

KW - Chromogenic

KW - Copper ion

KW - ICT

UR - http://www.scopus.com/inward/record.url?scp=64649104466&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2009.03.149

DO - 10.1016/j.tetlet.2009.03.149

M3 - Article

AN - SCOPUS:64649104466

SN - 0040-4039

VL - 50

SP - 2782

EP - 2786

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 23

ER -

ICT-based Cu(II)-sensing 9,10-anthraquinonecalix[4]crown

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this