Impedance spectroscopic analysis on effects of partial oxidation of TiN bottom electrode and microstructure of amorphous and crystalline HfO2 thin films on their bipolar resistive switching

Ji Wook Yoon, Jung Hor Yoon, Jong Heun Lee, Cheol Seong Hwang

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The electrical resistance switching (RS) properties of amorphous HfO 2 (a-HfO2) and crystalline HfO2 (c-HfO 2) thin films grown on a TiN substrate via atomic layer deposition were examined using DC current-voltage (I-V) sweep and AC impedance spectroscopic (IS) analyses. The rapid thermal annealing of the a-HfO 2 film at 500 °C under a N2 atmosphere for 5 min crystallized the HfO2 film and induced an interfacial TiON barrier layer. The a-HfO2 sample showed fluent bipolar RS performance with a high on/off ratio (∼500), whereas the c-HfO2 sample showed a much lower on/off ratio (<∼10), but its switching uniformity was better than that of a-HfO2. Such critical differences can be mainly attributed to the absence and presence of the TiON barrier layer in the a-HfO2 and c-HfO2 samples, respectively. The AC IS especially enabled the resistance states of the HfO2/Pt interface and the HfO 2/TiN interface to be separately examined during one complete switching cycle of each sample. Although the Pt/c-HfO2 interface has a Schottky barrier in the pristine state, it disappeared once the c-HfO 2 was electroformed and was not recovered even after the reset step. In contrast, the Pt/a-HfO2 interface partly recovered the Schottky barrier after the reset.

Original languageEnglish
Pages (from-to)6668-6678
Number of pages11
JournalNanoscale
Volume6
Issue number12
DOIs
Publication statusPublished - 2014 Jun 21

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Spectroscopic analysis
Crystalline materials
Thin films
Oxidation
Microstructure
Electrodes
Acoustic impedance
Atomic layer deposition
Rapid thermal annealing
Electric potential
Substrates

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Impedance spectroscopic analysis on effects of partial oxidation of TiN bottom electrode and microstructure of amorphous and crystalline HfO2 thin films on their bipolar resistive switching. / Yoon, Ji Wook; Yoon, Jung Hor; Lee, Jong Heun; Hwang, Cheol Seong.

In: Nanoscale, Vol. 6, No. 12, 21.06.2014, p. 6668-6678.

Research output: Contribution to journalArticle

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