Improved performance of sol–gel ZnO-based perovskite solar cells via TiCl4 interfacial modification

Yohan Ko, Yechan Kim, Seong Young Kong, Sakeerali Cheeran Kunnan, Yongseok Jun

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

CH3NH3PbI3 perovskite materials deposited on ZnO electron transport layers (ETLs) undergo decomposition during annealing in N2 atmosphere. We found that this decomposition can be retarded by restricting sublimation. Moreover, the decomposition upon thermal annealing is highly suppressed by TiCl4 treatment of the ZnO ETLs. Finally, we present a facile method for prolonged annealing in sol–gel ZnO-based perovskite solar cells, which exhibit a power conversion efficiency of 16.5% at a small area of 0.098 cm2 and 15.1% at a large area of 1 cm2 (active area) under AM 1.5 simulated sunlight illumination. This study shows that TiCl4 hydrolysis is an effective surface treatment for ZnO ETLs to be used in low-temperature and efficient sol–gel ZnO-based perovskite solar cells.

Original languageEnglish
Pages (from-to)157-163
Number of pages7
JournalSolar Energy Materials and Solar Cells
Volume183
DOIs
Publication statusPublished - 2018 Aug 15
Externally publishedYes

Fingerprint

Annealing
Decomposition
Sublimation
Perovskite
Conversion efficiency
Surface treatment
Hydrolysis
Pyrolysis
Lighting
Electron Transport
Perovskite solar cells
titanium tetrachloride
Temperature
perovskite

Keywords

  • Interfacial modification
  • Perovskite solar cell
  • Sol–gel ZnO
  • TiCl

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films

Cite this

Improved performance of sol–gel ZnO-based perovskite solar cells via TiCl4 interfacial modification. / Ko, Yohan; Kim, Yechan; Kong, Seong Young; Kunnan, Sakeerali Cheeran; Jun, Yongseok.

In: Solar Energy Materials and Solar Cells, Vol. 183, 15.08.2018, p. 157-163.

Research output: Contribution to journalArticle

Ko, Yohan ; Kim, Yechan ; Kong, Seong Young ; Kunnan, Sakeerali Cheeran ; Jun, Yongseok. / Improved performance of sol–gel ZnO-based perovskite solar cells via TiCl4 interfacial modification. In: Solar Energy Materials and Solar Cells. 2018 ; Vol. 183. pp. 157-163.
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AU - Jun, Yongseok

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