The grain-boundary conductivity of a 15 mol % calcia-stabilized zirconia specimen was increased about seven times by postsintering heat-treatment at 1300°C for 10 h. From the change in the crystallinity, morphology, and composition of the intergranular phase by heat-treatment, the de-wetting behavior of the intergranular phase due to crystallization was suggested to decrease the current constriction near the grain boundary. The postsintering heat-treatment was also effective at the high sintering temperature where adding A12O3 could not scavenge the resistive intergranular phase.
|Journal||Journal of the Electrochemical Society|
|Publication status||Published - 2003 Oct|
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Renewable Energy, Sustainability and the Environment
- Surfaces, Coatings and Films
- Materials Chemistry