Incorporation of various alcohol substituents to a metalloporphyrin platform for dramatic changes in morphologies of microcrystals

Seung Hyun Chae, Kyung Yeon Lee, Sung Jin Kim, Suk Joong Lee, Youngmee Kim

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Micro crystals with various morphologies have been successfully grown from readily accessible molecular platform [10,20-bis(2,6-dibutoxyphenyl)porphyrin]Sn(OH)2. Simple synthetic alteration makes this platform into various molecular building blocks using its axial coordination sites which trigger additional interactions and allow various crystal packing arrangements. We have demonstrated how apparently small modifications to building blocks can initiate significant changes in the morphologies and molecular packings of the corresponding solid state-state materials.

Original languageEnglish
Pages (from-to)40-44
Number of pages5
JournalInorganic Chemistry Communications
Volume69
DOIs
Publication statusPublished - 2016 Jul 1

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Keywords

  • Crystal
  • Molecular packing
  • Molecular platform
  • Morphology
  • Porphyrin

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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