Influence of environment on the measurement of rates of charge transport across AgTS/SAM//Ga2O3/EGaIn junctions

Jabulani R. Barber, Hyo Jae Yoon, Carleen M. Bowers, Martin M. Thuo, Benjamin Breiten, Diana M. Gooding, George M. Whitesides

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

This paper investigates the influence of the atmosphere used in the fabrication of top electrodes from the liquid eutectic of gallium and indium (EGaIn) (the so-called "EGaIn" electrodes), and in measurements of current density, J(V) (A/cm2), across self-assembled monolayers (SAMs) incorporated into Ag/SR//Ga2O3/EGaIn junctions, on values of J(V) obtained using these electrodes. A gas-tight measurement chamber was used to control the atmosphere in which the electrodes were formed, and also to control the environment in which the electrodes were used to measure current densities across SAM-based junctions. Seven different atmospheres-air, oxygen, nitrogen, argon, and ammonia, as well as air containing vapors of acetic acid or water-were surveyed using both "rough" conical-tip electrodes, and "smooth" hanging-drop electrodes. (The manipulation of the oxide film during the creation of the conical-tip electrodes leads to substantial, micrometer-scale roughness on the surface of the electrode, the extrusion of the drop creates a significantly smoother surface.) Comparing junctions using both geometries for the electrodes, across a SAM of n-dodecanethiol, in air, gave log |J|mean = -2.4 ± 0.4 for the conical tip, and log |J| mean = -0.6 ± 0.3 for the drop electrode (and, thus, δlog |J| ≈ 1.8); this increase in current density is attributed to a change in the effective electrical contact area of the junction. To establish the influence of the resistivity of the Ga2O3 film on values of J(V), junctions comprising a graphite electrode and a hanging-drop electrode were compared in an experiment where the electrodes did, and did not, have a surface oxide film; the presence of the oxide did not influence measurements of log |J(V)|, and therefore did not contribute to the electrical resistance of the electrode. However, the presence of an oxide film did improve the stability of junctions and increase the yield of working electrodes from ∼70% to ∼100%. Increasing the relative humidity (RH) in which J(V) was measured did not influence these values (across methyl (CH3)- or carboxyl (CO2H)-terminated SAMs) over the range typically encountered in the laboratory (20%-60% (RH)).

Original languageEnglish
Pages (from-to)3938-3947
Number of pages10
JournalChemistry of Materials
Volume26
Issue number13
DOIs
Publication statusPublished - 2014 Jul 8

Fingerprint

Gallium
Indium
Self assembled monolayers
Eutectics
Charge transfer
Electrodes
Oxide films
Current density
Atmospheric humidity
Air
Graphite electrodes
Acoustic impedance
Argon
Ammonia
Acetic acid
Acetic Acid
Oxides

ASJC Scopus subject areas

  • Materials Chemistry
  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Barber, J. R., Yoon, H. J., Bowers, C. M., Thuo, M. M., Breiten, B., Gooding, D. M., & Whitesides, G. M. (2014). Influence of environment on the measurement of rates of charge transport across AgTS/SAM//Ga2O3/EGaIn junctions. Chemistry of Materials, 26(13), 3938-3947. https://doi.org/10.1021/cm5014784

Influence of environment on the measurement of rates of charge transport across AgTS/SAM//Ga2O3/EGaIn junctions. / Barber, Jabulani R.; Yoon, Hyo Jae; Bowers, Carleen M.; Thuo, Martin M.; Breiten, Benjamin; Gooding, Diana M.; Whitesides, George M.

In: Chemistry of Materials, Vol. 26, No. 13, 08.07.2014, p. 3938-3947.

Research output: Contribution to journalArticle

Barber, JR, Yoon, HJ, Bowers, CM, Thuo, MM, Breiten, B, Gooding, DM & Whitesides, GM 2014, 'Influence of environment on the measurement of rates of charge transport across AgTS/SAM//Ga2O3/EGaIn junctions', Chemistry of Materials, vol. 26, no. 13, pp. 3938-3947. https://doi.org/10.1021/cm5014784
Barber, Jabulani R. ; Yoon, Hyo Jae ; Bowers, Carleen M. ; Thuo, Martin M. ; Breiten, Benjamin ; Gooding, Diana M. ; Whitesides, George M. / Influence of environment on the measurement of rates of charge transport across AgTS/SAM//Ga2O3/EGaIn junctions. In: Chemistry of Materials. 2014 ; Vol. 26, No. 13. pp. 3938-3947.
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