Inorganic Rubidium Cation as an Enhancer for Photovoltaic Performance and Moisture Stability of HC(NH2)2PbI3 Perovskite Solar Cells

Yun Hee Park, Inyoung Jeong, Seunghwan Bae, Hae Jung Son, Phillip Lee, Jinwoo Lee, Chul-Ho Lee, Min Jae Ko

Research output: Contribution to journalArticle

72 Citations (Scopus)

Abstract

Perovskite solar cells (PSCs) based on organic monovalent cation (methylammonium or formamidinium) have shown excellent optoelectronic properties with high efficiencies above 22%, threatening the status of silicon solar cells. However, critical issues of long-term stability have to be solved for commercialization. The severe weakness of the state-of-the-art PSCs against moisture originates mainly from the hygroscopic organic cations. Here, rubidium (Rb) is suggested as a promising candidate for an inorganic-organic mixed cation system to enhance moisture-tolerance and photovoltaic performances of formamidinium lead iodide (FAPbI3). Partial incorporation of Rb in FAPbI3 tunes the tolerance factor and stabilizes the photoactive perovskite structure. Phase conversion from hexagonal yellow FAPbI3 to trigonal black FAPbI3 becomes favored when Rb is introduced. The authors find that the absorbance and fluorescence lifetime of 5% Rb-incorporated FAPbI3 (Rb0.05FA0.95PbI3) are enhanced than bare FAPbI3. Rb0.05FA0.95PbI3-based PSCs exhibit a best power conversion efficiency of 17.16%, which is much higher than that of the FAPbI3 device (13.56%). Moreover, it is demonstrated that the Rb0.05FA0.95PbI3 film shows superior stability against high humidity (85%) and the full device made with the mixed perovskite exhibits remarkable long-term stability under ambient condition without encapsulation, retaining the high performance for 1000 h.

Original languageEnglish
JournalAdvanced Functional Materials
DOIs
Publication statusAccepted/In press - 2017

Fingerprint

Rubidium
rubidium
moisture
Cations
Moisture
solar cells
Positive ions
cations
Perovskite
Monovalent Cations
commercialization
Silicon solar cells
Iodides
retaining
Encapsulation
Optoelectronic devices
iodides
Conversion efficiency
humidity
Atmospheric humidity

Keywords

  • Fluorescence lifetimes
  • Inorganic-organic hybrids
  • Perovskites
  • Rubidium
  • Solar cells
  • Stability

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Condensed Matter Physics
  • Electrochemistry

Cite this

Inorganic Rubidium Cation as an Enhancer for Photovoltaic Performance and Moisture Stability of HC(NH2)2PbI3 Perovskite Solar Cells. / Park, Yun Hee; Jeong, Inyoung; Bae, Seunghwan; Son, Hae Jung; Lee, Phillip; Lee, Jinwoo; Lee, Chul-Ho; Ko, Min Jae.

In: Advanced Functional Materials, 2017.

Research output: Contribution to journalArticle

Park, Yun Hee ; Jeong, Inyoung ; Bae, Seunghwan ; Son, Hae Jung ; Lee, Phillip ; Lee, Jinwoo ; Lee, Chul-Ho ; Ko, Min Jae. / Inorganic Rubidium Cation as an Enhancer for Photovoltaic Performance and Moisture Stability of HC(NH2)2PbI3 Perovskite Solar Cells. In: Advanced Functional Materials. 2017.
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abstract = "Perovskite solar cells (PSCs) based on organic monovalent cation (methylammonium or formamidinium) have shown excellent optoelectronic properties with high efficiencies above 22{\%}, threatening the status of silicon solar cells. However, critical issues of long-term stability have to be solved for commercialization. The severe weakness of the state-of-the-art PSCs against moisture originates mainly from the hygroscopic organic cations. Here, rubidium (Rb) is suggested as a promising candidate for an inorganic-organic mixed cation system to enhance moisture-tolerance and photovoltaic performances of formamidinium lead iodide (FAPbI3). Partial incorporation of Rb in FAPbI3 tunes the tolerance factor and stabilizes the photoactive perovskite structure. Phase conversion from hexagonal yellow FAPbI3 to trigonal black FAPbI3 becomes favored when Rb is introduced. The authors find that the absorbance and fluorescence lifetime of 5{\%} Rb-incorporated FAPbI3 (Rb0.05FA0.95PbI3) are enhanced than bare FAPbI3. Rb0.05FA0.95PbI3-based PSCs exhibit a best power conversion efficiency of 17.16{\%}, which is much higher than that of the FAPbI3 device (13.56{\%}). Moreover, it is demonstrated that the Rb0.05FA0.95PbI3 film shows superior stability against high humidity (85{\%}) and the full device made with the mixed perovskite exhibits remarkable long-term stability under ambient condition without encapsulation, retaining the high performance for 1000 h.",
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T1 - Inorganic Rubidium Cation as an Enhancer for Photovoltaic Performance and Moisture Stability of HC(NH2)2PbI3 Perovskite Solar Cells

AU - Park, Yun Hee

AU - Jeong, Inyoung

AU - Bae, Seunghwan

AU - Son, Hae Jung

AU - Lee, Phillip

AU - Lee, Jinwoo

AU - Lee, Chul-Ho

AU - Ko, Min Jae

PY - 2017

Y1 - 2017

N2 - Perovskite solar cells (PSCs) based on organic monovalent cation (methylammonium or formamidinium) have shown excellent optoelectronic properties with high efficiencies above 22%, threatening the status of silicon solar cells. However, critical issues of long-term stability have to be solved for commercialization. The severe weakness of the state-of-the-art PSCs against moisture originates mainly from the hygroscopic organic cations. Here, rubidium (Rb) is suggested as a promising candidate for an inorganic-organic mixed cation system to enhance moisture-tolerance and photovoltaic performances of formamidinium lead iodide (FAPbI3). Partial incorporation of Rb in FAPbI3 tunes the tolerance factor and stabilizes the photoactive perovskite structure. Phase conversion from hexagonal yellow FAPbI3 to trigonal black FAPbI3 becomes favored when Rb is introduced. The authors find that the absorbance and fluorescence lifetime of 5% Rb-incorporated FAPbI3 (Rb0.05FA0.95PbI3) are enhanced than bare FAPbI3. Rb0.05FA0.95PbI3-based PSCs exhibit a best power conversion efficiency of 17.16%, which is much higher than that of the FAPbI3 device (13.56%). Moreover, it is demonstrated that the Rb0.05FA0.95PbI3 film shows superior stability against high humidity (85%) and the full device made with the mixed perovskite exhibits remarkable long-term stability under ambient condition without encapsulation, retaining the high performance for 1000 h.

AB - Perovskite solar cells (PSCs) based on organic monovalent cation (methylammonium or formamidinium) have shown excellent optoelectronic properties with high efficiencies above 22%, threatening the status of silicon solar cells. However, critical issues of long-term stability have to be solved for commercialization. The severe weakness of the state-of-the-art PSCs against moisture originates mainly from the hygroscopic organic cations. Here, rubidium (Rb) is suggested as a promising candidate for an inorganic-organic mixed cation system to enhance moisture-tolerance and photovoltaic performances of formamidinium lead iodide (FAPbI3). Partial incorporation of Rb in FAPbI3 tunes the tolerance factor and stabilizes the photoactive perovskite structure. Phase conversion from hexagonal yellow FAPbI3 to trigonal black FAPbI3 becomes favored when Rb is introduced. The authors find that the absorbance and fluorescence lifetime of 5% Rb-incorporated FAPbI3 (Rb0.05FA0.95PbI3) are enhanced than bare FAPbI3. Rb0.05FA0.95PbI3-based PSCs exhibit a best power conversion efficiency of 17.16%, which is much higher than that of the FAPbI3 device (13.56%). Moreover, it is demonstrated that the Rb0.05FA0.95PbI3 film shows superior stability against high humidity (85%) and the full device made with the mixed perovskite exhibits remarkable long-term stability under ambient condition without encapsulation, retaining the high performance for 1000 h.

KW - Fluorescence lifetimes

KW - Inorganic-organic hybrids

KW - Perovskites

KW - Rubidium

KW - Solar cells

KW - Stability

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