Intrinsic cascading contributions to the fifth- and seventh-order electronically off-resonant Raman spectroscopies

Minhaeng Cho, David A. Blank, Jaeyoung Sung, Kisam Park, Sangjoon Hahn, Graham R. Fleming

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

The cascading polarization contributing to the femtosecond fifth- and seventh-order coherent Raman scattering processes is obtained in terms of the third- and fifth-order Raman response functions. It is found that four cascading processes contribute to the fifth-order Raman scattering signal. In the case of the seventh-order Raman scattering, there are 34 possible cascading processes contributing to the seventh-order Raman scattering signal, and they are classified as χ(5)(3)- and χ(3)(3)Xχ(3)-types depending on the involved low-order nonlinear optical processes. Due to the complicated interference among these polarization fields, it may not be possible to experimentally measure the pure seventh-order Raman scattering signal without contamination from the cascaded contributions.

Original languageEnglish
Pages (from-to)2082-2094
Number of pages13
JournalJournal of Chemical Physics
Volume112
Issue number5
Publication statusPublished - 2000 Feb 1

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Raman spectroscopy
Raman scattering
Raman spectra
Polarization
Coherent scattering
coherent scattering
polarization
contamination
Contamination
interference

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Intrinsic cascading contributions to the fifth- and seventh-order electronically off-resonant Raman spectroscopies. / Cho, Minhaeng; Blank, David A.; Sung, Jaeyoung; Park, Kisam; Hahn, Sangjoon; Fleming, Graham R.

In: Journal of Chemical Physics, Vol. 112, No. 5, 01.02.2000, p. 2082-2094.

Research output: Contribution to journalArticle

Cho, Minhaeng ; Blank, David A. ; Sung, Jaeyoung ; Park, Kisam ; Hahn, Sangjoon ; Fleming, Graham R. / Intrinsic cascading contributions to the fifth- and seventh-order electronically off-resonant Raman spectroscopies. In: Journal of Chemical Physics. 2000 ; Vol. 112, No. 5. pp. 2082-2094.
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