Investigation into the effect of doping of boron and nitrogen atoms in the mechanical properties of single-layer polycrystalline graphene

Mohammadreza Izadifar, Rouzbeh Abadi, Amir Namazian Jam, Timon Rabczuk

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

In the present work, classical Molecular Dynamic simulations have been performed to peruse the effect of different grain sizes, temperatures and strain rates for different percentage of boron and nitrogen doping on the mechanical properties of polycrystalline graphene. Therefore, we studied 1%, 3%, 6% and 10% of boron or nitrogen doping for grain sizes of 1, 5, 10, 15, and 20 nm of graphene nanosheets at room temperature. The effect of different temperatures (100, 300, 600 and 900 K) on the mechanical response is investigated for five grain sizes (1, 5, 10, 15 and 20 nm) and 6% of boron or nitrogen doped polycrystalline graphene. Moreover, we studied different engineering strain rates on the mechanical response of six percentage of boron or nitrogen doped polycrystalline graphene for all simulation samples at 300 K. Our findings revealed that the mechanical response of polycrystalline graphene decrease as nitrogen or boron atoms are substituted into the nanosheet. By increasing of nitrogen atoms into polycrystalline graphene, a destructive affect occurs on the ultimate failure strain and tensile strength. Furthermore, the tensile strength tends to increase as the grain sizes increase from 1 to 20 nm. On the contrary, the failure strain has a tendency to decrease. As the temperatures increase in boron or nitrogen doped polycrystalline graphene, the tensile strength decreases as well as the failure strain. An increasing trend has been observed for mechanical properties of boron or nitrogen doped polycrystalline graphene as the strain rate increase. However, the effect of nitrogen on the tensile strength of nanosheet is more significant compared to boron doped nanosheet.

Original languageEnglish
Pages (from-to)435-447
Number of pages13
JournalComputational Materials Science
Volume138
DOIs
Publication statusPublished - 2017 Oct 1
Externally publishedYes

Keywords

  • Boron or nitrogen doping
  • Mechanical response
  • Molecular dynamic simulation
  • Polycrystalline graphene
  • Strain rate effect
  • Temperature effect

ASJC Scopus subject areas

  • Computer Science(all)
  • Chemistry(all)
  • Materials Science(all)
  • Mechanics of Materials
  • Physics and Astronomy(all)
  • Computational Mathematics

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