Investigation of the effect of the structure of large-area carbon nanotube/fuel composites on energy generation from thermopower waves

Hayoung Hwang, Taehan Yeo, Jo Eun Um, Kang Yeol Lee, Hong Seok Kim, Jae Hee Han, Woo Jae Kim, Wonjoon Choi

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Thermopower waves are a recently developed energy conversion concept utilizing dynamic temperature and chemical potential gradients to harvest electrical energy while the combustion wave propagates along the hybrid layers of nanomaterials and chemical fuels. The intrinsic properties of the core nanomaterials and chemical fuels in the hybrid composites can broadly affect the energy generation, as well as the combustion process, of thermopower waves. So far, most research has focused on the application of new core nanomaterials to enhance energy generation. In this study, we demonstrate that the alignment of core nanomaterials can significantly influence a number of aspects of the thermopower waves, while the nanomaterials involved are identical carbon nanotubes (CNTs). Diversely structured, large-area CNT/fuel composites of one-dimensional aligned CNT arrays (1D CNT arrays), randomly oriented CNT films (2D CNT films), and randomly aggregated bulk CNT clusters (3D CNT clusters) were fabricated to evaluate the energy generation, as well as the propagation of the thermal wave, from thermopower waves. The more the core nanostructures were aligned, the less inversion of temperature gradients and the less cross-propagation of multiple thermopower waves occurred. These characteristics of the aligned structures prevented the cancellation of charge carrier movements among the core nanomaterials and produced the relative enhancement of the energy generation and the specific power with a single-polarity voltage signal. Understanding this effect of structure on energy generation from thermopower waves can help in the design of optimized hybrid composites of nanomaterials and fuels, especially designs based on the internal alignment of the materials. More generally, we believe that this work provides clues to the process of chemical to thermal to electrical energy conversion inside/outside hybrid nanostructured materials.

Original languageEnglish
JournalNanoscale Research Letters
Volume9
Issue number1
DOIs
Publication statusPublished - 2014 Jan 1

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Carbon Nanotubes
Thermoelectric power
Nanostructured materials
Carbon nanotubes
carbon nanotubes
composite materials
Composite materials
chemical fuels
hybrid composites
energy
energy conversion
electric power
Energy conversion
alignment
potential gradients
propagation
Chemical potential
Hybrid materials
flame propagation
Charge carriers

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Investigation of the effect of the structure of large-area carbon nanotube/fuel composites on energy generation from thermopower waves. / Hwang, Hayoung; Yeo, Taehan; Um, Jo Eun; Lee, Kang Yeol; Kim, Hong Seok; Han, Jae Hee; Kim, Woo Jae; Choi, Wonjoon.

In: Nanoscale Research Letters, Vol. 9, No. 1, 01.01.2014.

Research output: Contribution to journalArticle

Hwang, Hayoung ; Yeo, Taehan ; Um, Jo Eun ; Lee, Kang Yeol ; Kim, Hong Seok ; Han, Jae Hee ; Kim, Woo Jae ; Choi, Wonjoon. / Investigation of the effect of the structure of large-area carbon nanotube/fuel composites on energy generation from thermopower waves. In: Nanoscale Research Letters. 2014 ; Vol. 9, No. 1.
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