Ionic recognition by proton-ionizable lariat ethers and their polymers

Richard A. Bartsch, Jong Seung Kim, Uriel Olsher, D. W. David, P. Purkiss, Visvanathan Ramesh, N. Kent Dailey, Takashi Hayashita

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

To probe the influence of structural variation within dibenzo-16-crown-5-oxyacetic acids upon the selectivity of alkali metal cation separations by solvent extraction and liquid membrane transport processes, studies have now been conducted in homogeneous solution by NMR spectroscopy and titration calorimetry and in the solid state. Condensation polymerization of such proton-ionizable lariat ethers with formaldehyde produces a new class of ion-exchange resins which contain cyclic polyether binding sites as well as ion-exchange site for metal ion complexation.

Original languageEnglish
Pages (from-to)399-402
Number of pages4
JournalPure and Applied Chemistry
Volume65
Issue number3
DOIs
Publication statusPublished - 1993 Jan 1
Externally publishedYes

Fingerprint

Ion Exchange Resins
Alkali Metals
Liquid membranes
Ion exchange resins
Ethers
Polyethers
Alkali metals
Solvent extraction
Calorimetry
Binding sites
Polycondensation
Complexation
Titration
Formaldehyde
Nuclear magnetic resonance spectroscopy
Metal ions
Cations
Protons
Ion exchange
Polymers

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Bartsch, R. A., Kim, J. S., Olsher, U., David, D. W., Purkiss, P., Ramesh, V., ... Hayashita, T. (1993). Ionic recognition by proton-ionizable lariat ethers and their polymers. Pure and Applied Chemistry, 65(3), 399-402. https://doi.org/10.1351/pac199365030399

Ionic recognition by proton-ionizable lariat ethers and their polymers. / Bartsch, Richard A.; Kim, Jong Seung; Olsher, Uriel; David, D. W.; Purkiss, P.; Ramesh, Visvanathan; Dailey, N. Kent; Hayashita, Takashi.

In: Pure and Applied Chemistry, Vol. 65, No. 3, 01.01.1993, p. 399-402.

Research output: Contribution to journalArticle

Bartsch, RA, Kim, JS, Olsher, U, David, DW, Purkiss, P, Ramesh, V, Dailey, NK & Hayashita, T 1993, 'Ionic recognition by proton-ionizable lariat ethers and their polymers', Pure and Applied Chemistry, vol. 65, no. 3, pp. 399-402. https://doi.org/10.1351/pac199365030399
Bartsch, Richard A. ; Kim, Jong Seung ; Olsher, Uriel ; David, D. W. ; Purkiss, P. ; Ramesh, Visvanathan ; Dailey, N. Kent ; Hayashita, Takashi. / Ionic recognition by proton-ionizable lariat ethers and their polymers. In: Pure and Applied Chemistry. 1993 ; Vol. 65, No. 3. pp. 399-402.
@article{f4a85559e70f4eee92f5433d3bba606f,
title = "Ionic recognition by proton-ionizable lariat ethers and their polymers",
abstract = "To probe the influence of structural variation within dibenzo-16-crown-5-oxyacetic acids upon the selectivity of alkali metal cation separations by solvent extraction and liquid membrane transport processes, studies have now been conducted in homogeneous solution by NMR spectroscopy and titration calorimetry and in the solid state. Condensation polymerization of such proton-ionizable lariat ethers with formaldehyde produces a new class of ion-exchange resins which contain cyclic polyether binding sites as well as ion-exchange site for metal ion complexation.",
author = "Bartsch, {Richard A.} and Kim, {Jong Seung} and Uriel Olsher and David, {D. W.} and P. Purkiss and Visvanathan Ramesh and Dailey, {N. Kent} and Takashi Hayashita",
year = "1993",
month = "1",
day = "1",
doi = "10.1351/pac199365030399",
language = "English",
volume = "65",
pages = "399--402",
journal = "Pure and Applied Chemistry",
issn = "0033-4545",
publisher = "IUPAC Secretariat",
number = "3",

}

TY - JOUR

T1 - Ionic recognition by proton-ionizable lariat ethers and their polymers

AU - Bartsch, Richard A.

AU - Kim, Jong Seung

AU - Olsher, Uriel

AU - David, D. W.

AU - Purkiss, P.

AU - Ramesh, Visvanathan

AU - Dailey, N. Kent

AU - Hayashita, Takashi

PY - 1993/1/1

Y1 - 1993/1/1

N2 - To probe the influence of structural variation within dibenzo-16-crown-5-oxyacetic acids upon the selectivity of alkali metal cation separations by solvent extraction and liquid membrane transport processes, studies have now been conducted in homogeneous solution by NMR spectroscopy and titration calorimetry and in the solid state. Condensation polymerization of such proton-ionizable lariat ethers with formaldehyde produces a new class of ion-exchange resins which contain cyclic polyether binding sites as well as ion-exchange site for metal ion complexation.

AB - To probe the influence of structural variation within dibenzo-16-crown-5-oxyacetic acids upon the selectivity of alkali metal cation separations by solvent extraction and liquid membrane transport processes, studies have now been conducted in homogeneous solution by NMR spectroscopy and titration calorimetry and in the solid state. Condensation polymerization of such proton-ionizable lariat ethers with formaldehyde produces a new class of ion-exchange resins which contain cyclic polyether binding sites as well as ion-exchange site for metal ion complexation.

UR - http://www.scopus.com/inward/record.url?scp=0000514134&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000514134&partnerID=8YFLogxK

U2 - 10.1351/pac199365030399

DO - 10.1351/pac199365030399

M3 - Article

VL - 65

SP - 399

EP - 402

JO - Pure and Applied Chemistry

JF - Pure and Applied Chemistry

SN - 0033-4545

IS - 3

ER -