Isoindigo-based polymer solar cells with high open circuit voltages up to 1.01 v

Gi Eun Park, Suna Choi, Jicheol Shin, Min Ju Cho, Dong Hoon Choi

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Isoindigo-based copolymers containing non-fluorinated (PIIDBT) and fluorinated bithiophene moieties (PIIDFBT) were synthesized. The replacement of hydrogen atoms with electronegative fluorine atom attained the intramolecular noncovalent interactions in conjugated polymer structure employing the concept of conformational locks. Furthermore, the fluorine characteristics as substituent atoms tuned the electron withdrawing ability and made the HOMO energy levels of fluorinated moieties deeper (-5.79 eV) than that of non-fluorinated polymer (-5.54 eV). As a result, the photovoltaic performance of PIIDFBT was improved by increasing its open circuit voltage (Voc) up to 1.01 V, resulting in a power conversion efficiency of 6.21%. The PIIDFBT with high Voc can be recognized as a promising candidate for both single junction and multi-junction photovoltaics.

Original languageEnglish
Pages (from-to)157-163
Number of pages7
JournalOrganic Electronics: physics, materials, applications
Volume34
DOIs
Publication statusPublished - 2016 Jul 1

Fingerprint

Open circuit voltage
open circuit voltage
fluorine
high voltages
Fluorine
solar cells
Atoms
polymers
atoms
hydrogen atoms
copolymers
energy levels
Conjugated polymers
Electron energy levels
Conversion efficiency
Hydrogen
Polymers
Copolymers
electrons
Electrons

Keywords

  • Fluorinated moiety
  • Isoindigo
  • Open circuit voltage
  • Polymer solar cells

ASJC Scopus subject areas

  • Biomaterials
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Electrical and Electronic Engineering
  • Chemistry(all)
  • Condensed Matter Physics

Cite this

Isoindigo-based polymer solar cells with high open circuit voltages up to 1.01 v. / Park, Gi Eun; Choi, Suna; Shin, Jicheol; Cho, Min Ju; Choi, Dong Hoon.

In: Organic Electronics: physics, materials, applications, Vol. 34, 01.07.2016, p. 157-163.

Research output: Contribution to journalArticle

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abstract = "Isoindigo-based copolymers containing non-fluorinated (PIIDBT) and fluorinated bithiophene moieties (PIIDFBT) were synthesized. The replacement of hydrogen atoms with electronegative fluorine atom attained the intramolecular noncovalent interactions in conjugated polymer structure employing the concept of conformational locks. Furthermore, the fluorine characteristics as substituent atoms tuned the electron withdrawing ability and made the HOMO energy levels of fluorinated moieties deeper (-5.79 eV) than that of non-fluorinated polymer (-5.54 eV). As a result, the photovoltaic performance of PIIDFBT was improved by increasing its open circuit voltage (Voc) up to 1.01 V, resulting in a power conversion efficiency of 6.21{\%}. The PIIDFBT with high Voc can be recognized as a promising candidate for both single junction and multi-junction photovoltaics.",
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T1 - Isoindigo-based polymer solar cells with high open circuit voltages up to 1.01 v

AU - Park, Gi Eun

AU - Choi, Suna

AU - Shin, Jicheol

AU - Cho, Min Ju

AU - Choi, Dong Hoon

PY - 2016/7/1

Y1 - 2016/7/1

N2 - Isoindigo-based copolymers containing non-fluorinated (PIIDBT) and fluorinated bithiophene moieties (PIIDFBT) were synthesized. The replacement of hydrogen atoms with electronegative fluorine atom attained the intramolecular noncovalent interactions in conjugated polymer structure employing the concept of conformational locks. Furthermore, the fluorine characteristics as substituent atoms tuned the electron withdrawing ability and made the HOMO energy levels of fluorinated moieties deeper (-5.79 eV) than that of non-fluorinated polymer (-5.54 eV). As a result, the photovoltaic performance of PIIDFBT was improved by increasing its open circuit voltage (Voc) up to 1.01 V, resulting in a power conversion efficiency of 6.21%. The PIIDFBT with high Voc can be recognized as a promising candidate for both single junction and multi-junction photovoltaics.

AB - Isoindigo-based copolymers containing non-fluorinated (PIIDBT) and fluorinated bithiophene moieties (PIIDFBT) were synthesized. The replacement of hydrogen atoms with electronegative fluorine atom attained the intramolecular noncovalent interactions in conjugated polymer structure employing the concept of conformational locks. Furthermore, the fluorine characteristics as substituent atoms tuned the electron withdrawing ability and made the HOMO energy levels of fluorinated moieties deeper (-5.79 eV) than that of non-fluorinated polymer (-5.54 eV). As a result, the photovoltaic performance of PIIDFBT was improved by increasing its open circuit voltage (Voc) up to 1.01 V, resulting in a power conversion efficiency of 6.21%. The PIIDFBT with high Voc can be recognized as a promising candidate for both single junction and multi-junction photovoltaics.

KW - Fluorinated moiety

KW - Isoindigo

KW - Open circuit voltage

KW - Polymer solar cells

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