Kinetic study on phosphate removal from aqueous solution by biochar derived from peanut shell as renewable adsorptive media

K. W. Jung, M. J. Hwang, K. H. Ahn, Yong Sik Ok

Research output: Contribution to journalArticle

52 Citations (Scopus)

Abstract

As an alternative strategy for phosphate removal, biochar (black carbon) has characteristics superior to those of widely used adsorptive media, from both economic and environmental points of view. In this study, various types of biochar derived from oak wood, bamboo wood, maize residue, soybean stover, and peanut shell were tested for evaluation of phosphate removal. After 24 h of reaction time, the phosphate removal was limited (2.0–9.4 %) in case of general adsorptive media. However, interestingly, among various biochars, peanut shell-derived biochar (PSB) exhibited the best performance, showing the highest phosphate removal rate, 61.3 % (3.8 mg PO4−P g PSB−1). We attribute this high value to the proper structural properties of PSB, such as BET-specific surface area of 348.96 m2 g−1 and mineral/phosphorus ratio (Mg/P = 3.46 and Ca/P = 47.6). Adsorption equilibrium and kinetics of phosphate at different temperature (10, 20, and 30 °C) were well explained in the whole experimental region by Langmuir isotherm and pseudo-second-order kinetic models, respectively. The maximum adsorption capacity of PSB was 6.79 mg g−1 for phosphate at 30 °C. These findings suggest that PSB has great potential as an alternative and renewable adsorptive media for phosphate removal.

Original languageEnglish
Pages (from-to)3363-3372
Number of pages10
JournalInternational Journal of Environmental Science and Technology
Volume12
Issue number10
DOIs
Publication statusPublished - 2015 Oct 20
Externally publishedYes

Fingerprint

peanut hulls
biochar
aqueous solutions
Phosphates
aqueous solution
phosphates
shell
kinetics
Kinetics
phosphate
adsorption
Adsorption
Wood
bamboo
black carbon
Soot
soybean
Bamboo
stover
isotherm

Keywords

  • Biochar
  • Black carbon
  • Charcoal
  • Mineral/phosphorus ratio
  • Peanut shells
  • Phosphate removal

ASJC Scopus subject areas

  • Agricultural and Biological Sciences(all)
  • Environmental Chemistry
  • Environmental Engineering

Cite this

Kinetic study on phosphate removal from aqueous solution by biochar derived from peanut shell as renewable adsorptive media. / Jung, K. W.; Hwang, M. J.; Ahn, K. H.; Ok, Yong Sik.

In: International Journal of Environmental Science and Technology, Vol. 12, No. 10, 20.10.2015, p. 3363-3372.

Research output: Contribution to journalArticle

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