Kinetics of Hg adsorption onto noncrystalline Al hydroxide as influenced by low-molecular-weight organic ligands

Jae E. Yang, Yong Sik Ok

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

This study was conducted to investigate the kinetics of Hg adsorption by noncrystalline Al hydroxide as influenced by various pH conditions and cysteine (cys), glycine (gly), and citric acid (cit), which have different structures and functionalities, as low-molecular-weight organic ligands using the GEOCHEM-PC software. The influence of these organic ligands on the kinetics of Hg adsorption varied according to their concentration, structure, and functionality and pH. The adsorption of Hg followed multiple first order kinetics with initial rapid adsorption, followed by slow adsorption. Cysteine suppressed or enhanced Hg adsorption, depending on pH and its concentration. Glycine and citric acid exerted suppressing and enhancing effects, respectively, with the exception of at pH 4.5 and at lower concentrations, at which no influence was observed as compared to the control. Two mechanisms were thought to mediate the adsorption of Hg(II); specific surface complexation in the control, cysteine and glycine systems, and ligand exchange in the citric acid system. The Hg adsorption at all levels of organic ligands decreased with increasing pH, with the exception of at the higher concentration of cysteine, at which the reverse trend was observed. The influence of organic ligands on the dynamics of Hg in the freshwater environment merits further study.

Original languageEnglish
Pages (from-to)124-135
Number of pages12
JournalArchives of Agronomy and Soil Science
Volume63
Issue number1
DOIs
Publication statusPublished - 2017 Jan 2
Externally publishedYes

Fingerprint

hydroxides
ligand
hydroxide
adsorption
molecular weight
kinetics
cysteine
citric acid
glycine (amino acid)
freshwater environment
ligands
complexation
software

Keywords

  • adsorption
  • Al(OH)
  • Hg(II)
  • organic ligands
  • speciation

ASJC Scopus subject areas

  • Agronomy and Crop Science
  • Soil Science

Cite this

Kinetics of Hg adsorption onto noncrystalline Al hydroxide as influenced by low-molecular-weight organic ligands. / Yang, Jae E.; Ok, Yong Sik.

In: Archives of Agronomy and Soil Science, Vol. 63, No. 1, 02.01.2017, p. 124-135.

Research output: Contribution to journalArticle

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