Long-lived metastable bcc phase during ordering of micelles

Joona Bang, Timothy P. Lodge

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The formation of metastable bcc phase at high temperature ordering of micelles was investigated. Anionic polymerization was used to synthesize a symmetric poly(styrene-b-isoprene) (SI) diblock copolymer. The metastable bcc phase nucleated first upon heating and then it transformed over the time to the stable fcc phase. The fcc phase was found to transform into an equilibrium bcc phase at higher temperatures. The results show that bcc nucleates more readily from a melt of spheres.

Original languageEnglish
Article number245701
JournalPhysical review letters
Volume93
Issue number24
DOIs
Publication statusPublished - 2004 Dec 10

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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