Low-temperature Co-fired NPO-type ceramic composition for high-frequency capacitor applications

Dong-Wan Kim, Jeong Ryeol Kim, Seo Yong Cho, Jianjiang Bian, Kug Sun Hong

Research output: Contribution to journalArticle

Abstract

Low-loss dielectrics of the temperature specification NPO are prepared from the system BaTi4O9 containing Zn-B-O glass. It was found that the addition of small amount of glass to BaTi4O 9lowered the sintering temperature of below 950°C, allowing high electrical conductivity metallization with Cu. High frequency multilayer ceramic chip capacitors (MLCCs) were fabricated. The copper electrodes, combined with low fire BaTi4O9 give high Qs of up to 100 at GHz frequencies. The degradation mechanisms of dielectric properties in reducing atmosphere have been studied. The investigations of the dielectric properties at low frequency have enabled us to explain the presence of the mobile charge carriers that cause space-charge polarization in low-fired BaTi4O9 samples. Reliability of the compositions with Cu electrodes was also investigated using transmission electron microscopy and X-ray diffraction.

Original languageEnglish
Pages (from-to)385-388
Number of pages4
JournalKey Engineering Materials
Volume247
Publication statusPublished - 2003 Sep 1
Externally publishedYes

Fingerprint

Dielectric properties
Capacitors
Glass
Electrodes
Dielectric losses
Metallizing
Charge carriers
Chemical analysis
Electric space charge
Copper
Multilayers
Fires
Sintering
Polarization
Transmission electron microscopy
Specifications
X ray diffraction
Degradation
Temperature
Electric Conductivity

Keywords

  • BaTiO
  • Co-Fired
  • Cu Electrodes
  • NPO

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Ceramics and Composites

Cite this

Low-temperature Co-fired NPO-type ceramic composition for high-frequency capacitor applications. / Kim, Dong-Wan; Kim, Jeong Ryeol; Cho, Seo Yong; Bian, Jianjiang; Hong, Kug Sun.

In: Key Engineering Materials, Vol. 247, 01.09.2003, p. 385-388.

Research output: Contribution to journalArticle

Kim, Dong-Wan ; Kim, Jeong Ryeol ; Cho, Seo Yong ; Bian, Jianjiang ; Hong, Kug Sun. / Low-temperature Co-fired NPO-type ceramic composition for high-frequency capacitor applications. In: Key Engineering Materials. 2003 ; Vol. 247. pp. 385-388.
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