Luminescence characteristics of Y2SiO5:Tb phosphor particles directly prepared by the spray pyrolysis method

Yun Chan Kang, Ignatius Wuled Lenggoro, Kikuo Okuyama, Seung Bin Park

Research output: Contribution to journalArticle

91 Citations (Scopus)

Abstract

Tb-doped Y2SiO5 phosphor particles were prepared directly by a continuous droplet-to-particle preparation process using an ultrasonic spray generator. The photoluminescence characteristics of as-prepared and calcined particles were investigated. The particles of Y2SiO5 prepared below 1100 °C had poor crystallinity because of the short residence time of the particles inside the hot wall reactor, while the particles of Y2SiO5 prepared at 1200 °C had sharp crystallinity. The crystal structure of Y2SiO5 particles was changed from the X1 to X2 type after calcining above 1400 °C. Both prepared and calcined particles had spherical morphology, submicron size, and narrow size distribution. Agglomeration of particles did not occur even after calcining at 1200 °C. The prepared Y2SiO5:Tb particles absorbed excitation energy in the range from 220 to 325 nm, and the maximum excitation wavelength was near 240 nm. The main emission peak was 538 nm. The optimum brightness was obtained at the doping concentration of 4 atom %. The activation of terbium occurred directly even at short reaction times inside the hot wall reactor. The brightness of as-prepared particles increased with increasing temperature because of good activation and crystallization in high temperatures. The PL intensity of as-prepared particles at 1200 °C was 96% in comparison with maximum intensity of calcined particles.

Original languageEnglish
Pages (from-to)1227-1230
Number of pages4
JournalJournal of the Electrochemical Society
Volume146
Issue number3
DOIs
Publication statusPublished - 1999 Mar 1
Externally publishedYes

Fingerprint

Spray pyrolysis
Phosphors
phosphors
pyrolysis
sprayers
Luminescence
Luminance
Chemical activation
Terbium
luminescence
Excitation energy
Crystallization
Photoluminescence
Agglomeration
Crystal structure
Ultrasonics
Doping (additives)
Wavelength
Atoms
Temperature

ASJC Scopus subject areas

  • Electrochemistry
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Cite this

Luminescence characteristics of Y2SiO5:Tb phosphor particles directly prepared by the spray pyrolysis method. / Kang, Yun Chan; Lenggoro, Ignatius Wuled; Okuyama, Kikuo; Park, Seung Bin.

In: Journal of the Electrochemical Society, Vol. 146, No. 3, 01.03.1999, p. 1227-1230.

Research output: Contribution to journalArticle

Kang, Yun Chan ; Lenggoro, Ignatius Wuled ; Okuyama, Kikuo ; Park, Seung Bin. / Luminescence characteristics of Y2SiO5:Tb phosphor particles directly prepared by the spray pyrolysis method. In: Journal of the Electrochemical Society. 1999 ; Vol. 146, No. 3. pp. 1227-1230.
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