TY - JOUR
T1 - Magnetic Pd@Fe3O4 composite nanostructure as recoverable catalyst for sonoelectrohybrid degradation of Ibuprofen
AU - Thokchom, Binota
AU - Qiu, Pengpeng
AU - Cui, Mingcan
AU - Park, Beomguk
AU - Pandit, Aniruddha B.
AU - Khim, Jeehyeong
N1 - Funding Information:
This work was supported by the Korea Institute of Energy Technology Evaluation and Planning ( KETEP , 20152510101820 ), Korea Mine Reclamation Corporation ( MIRECO , Q1512631) and Korea Government Scholarship Programme provided by National Institute for International Education ( NIIED ), Ministry of Education.
Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - In the present research, the degradation of an emerging pharmaceutical micro-pollutant, Ibuprofen (IBP) by using Pd@Fe3O4 and a hybrid sono-electrolytical (US/EC) treatment system has been demonstrated for the first time. The magnetically separable nanocomposite, Pd@Fe3O4 catalyst was synthesized following co-precipitation method to enhance the efficiency of US/EC system. The synthesized catalyst showed a strong reusable property even after applying for five times and in all the five cases, 100% degradation of IBP was maintained. It not only enhanced the IBP degradation rate, but also reduced the energy consumption of the system by ∼35%. Its strong magnetization value of 64.27 emu g-1 made it easily separable. Hence, a comprehensive knowledge on the application of combined energy based US/EC system and magnetically separable multifunctional catalysts for degradation of intractable pollutants like Ibuprofen was achieved, assuring that US/EC can be an effective option for IBP treatment.
AB - In the present research, the degradation of an emerging pharmaceutical micro-pollutant, Ibuprofen (IBP) by using Pd@Fe3O4 and a hybrid sono-electrolytical (US/EC) treatment system has been demonstrated for the first time. The magnetically separable nanocomposite, Pd@Fe3O4 catalyst was synthesized following co-precipitation method to enhance the efficiency of US/EC system. The synthesized catalyst showed a strong reusable property even after applying for five times and in all the five cases, 100% degradation of IBP was maintained. It not only enhanced the IBP degradation rate, but also reduced the energy consumption of the system by ∼35%. Its strong magnetization value of 64.27 emu g-1 made it easily separable. Hence, a comprehensive knowledge on the application of combined energy based US/EC system and magnetically separable multifunctional catalysts for degradation of intractable pollutants like Ibuprofen was achieved, assuring that US/EC can be an effective option for IBP treatment.
KW - Electrolysis
KW - Hybrid
KW - Ibuprofen
KW - Pd@FeO
KW - Sonolysis
UR - http://www.scopus.com/inward/record.url?scp=84974602093&partnerID=8YFLogxK
U2 - 10.1016/j.ultsonch.2016.05.030
DO - 10.1016/j.ultsonch.2016.05.030
M3 - Article
C2 - 27773244
AN - SCOPUS:84974602093
VL - 34
SP - 262
EP - 272
JO - Ultrasonics Sonochemistry
JF - Ultrasonics Sonochemistry
SN - 1350-4177
ER -
