Magnetic properties of reactively sputtered Fe1-xO and Fe 3O4 thin films

Young-geun Kim, M. Oliveria

Research output: Contribution to journalArticle

50 Citations (Scopus)

Abstract

We have investigated the magnetic properties of Fe3O4 thin films with thicknesses below 1000 Å. Previous reports had indicated an anomalous decrease in the saturation magnetization of Fe3O 4 films with thicknesses below 700 Å. The films were prepared by reactive rf magnetron sputtering and effects of film thickness, oxygen flow rate, and substrate temperature were examined. A region of acceptable magnetic properties, which do not vary with film thickness, for Fe3O 4 films has been found at both RT and 400°C. Within the processing region for single-phase Fe3O4, the magnetic properties did not vary significantly with oxygen partial pressure but did change with substrate temperature. The RT films are characterized by low saturation magnetization, 250 emu/cm3, and modest coercivity, 250 Oe. The films at 400°C have a higher saturation magnetization, 330 emu/cm 3, but also a higher coercivity, 450 Oe. The increased saturation magnetization at higher temperature results from the higher film density and lower degree of cation disorder; the higher coercivity at 400°C is anomalous. In addition, at RT we have discovered a processing region where ferrimagnetic wüstite, Fe1-xO, is formed. The Fe1-xO films have good soft magnetic properties and warrant further study.

Original languageEnglish
Pages (from-to)431-437
Number of pages7
JournalJournal of Applied Physics
Volume75
Issue number1
DOIs
Publication statusPublished - 1994 Dec 1
Externally publishedYes

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magnetic properties
thin films
coercivity
saturation
magnetization
film thickness
oxygen
partial pressure
magnetron sputtering
flow velocity
disorders
cations
temperature

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)

Cite this

Magnetic properties of reactively sputtered Fe1-xO and Fe 3O4 thin films. / Kim, Young-geun; Oliveria, M.

In: Journal of Applied Physics, Vol. 75, No. 1, 01.12.1994, p. 431-437.

Research output: Contribution to journalArticle

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abstract = "We have investigated the magnetic properties of Fe3O4 thin films with thicknesses below 1000 {\AA}. Previous reports had indicated an anomalous decrease in the saturation magnetization of Fe3O 4 films with thicknesses below 700 {\AA}. The films were prepared by reactive rf magnetron sputtering and effects of film thickness, oxygen flow rate, and substrate temperature were examined. A region of acceptable magnetic properties, which do not vary with film thickness, for Fe3O 4 films has been found at both RT and 400°C. Within the processing region for single-phase Fe3O4, the magnetic properties did not vary significantly with oxygen partial pressure but did change with substrate temperature. The RT films are characterized by low saturation magnetization, 250 emu/cm3, and modest coercivity, 250 Oe. The films at 400°C have a higher saturation magnetization, 330 emu/cm 3, but also a higher coercivity, 450 Oe. The increased saturation magnetization at higher temperature results from the higher film density and lower degree of cation disorder; the higher coercivity at 400°C is anomalous. In addition, at RT we have discovered a processing region where ferrimagnetic w{\"u}stite, Fe1-xO, is formed. The Fe1-xO films have good soft magnetic properties and warrant further study.",
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