Measuring Competing Recombination Losses in a Significantly Reduced Langevin System by Steady-State Photoinduced Absorption and Photocurrent Spectroscopy

Le Quang Phuong, Seyed Mehrdad Hosseini, Chang Woo Koh, Han Young Woo, Safa Shoaee

Research output: Contribution to journalArticle

Abstract

Understanding and disentangling photophysical properties of long-lived photoexcitations in bulk heterojunction (BHJ) solar cells, which contribute mostly to photocurrent, provide essential guidelines to their improvement. However, to construct improved physical models, their rational design relies on reliable measurement techniques for charge recombination. Here, we combine photocurrent and photoinduced absorption spectroscopy (PCPIA) to directly probe the free carrier concentration and investigate loss mechanisms of long-lived excitations in nearly 10% efficient PPDT2FBT/PC70BM BHJ solar cells under steady-state operational conditions. From the PCPIA data obtained under open-circuit and short-circuit conditions, the absorption cross section and the concentration of photoexcitations are obtained. This material system exhibits an exceptionally low bimolecular recombination rate, about 300 times smaller than the diffusion-controlled electron and hole encounter rate. Furthermore, we observe that the fill factor is limited by losses originating from long-lived photoexcitations undergoing dispersive bimolecular recombination.

Original languageEnglish
JournalJournal of Physical Chemistry C
DOIs
Publication statusAccepted/In press - 2019 Jan 1

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Photoexcitation
Photocurrents
photoexcitation
photocurrents
absorption spectroscopy
Spectroscopy
Absorption spectroscopy
Heterojunctions
heterojunctions
Solar cells
solar cells
spectroscopy
short circuits
encounters
Short circuit currents
absorption cross sections
Carrier concentration
Electrons
Networks (circuits)
probes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Measuring Competing Recombination Losses in a Significantly Reduced Langevin System by Steady-State Photoinduced Absorption and Photocurrent Spectroscopy. / Phuong, Le Quang; Hosseini, Seyed Mehrdad; Koh, Chang Woo; Woo, Han Young; Shoaee, Safa.

In: Journal of Physical Chemistry C, 01.01.2019.

Research output: Contribution to journalArticle

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