Mechanistic insights into oxidative decomposition of exo- tetrahydrodicyclopentadiene

Sun Hee Park, Cheong Hoon Kwon, Joongyeon Kim, Jeong Sik Han, Byung Hun Jeong, Hogyu Han, Sung Hyun Kim

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

We investigated the decomposition of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of O 2 at various temperatures. It was found that conversion of exo-THDCP was faster in the presence of O2 as compared to in its absence. The O2-induced increase in the conversion of exo-THDCP was hardly affected by variations in temperature. In addition, the O2-induced increase in the rate of C10 product formation was higher than those of <C10 and >C10. We proposed the mechanism for the oxidative decomposition of exo-THDCP, which occurs independently of its thermal decomposition and induces distinct product formation near and below its thermal decomposition starting temperature.

Original languageEnglish
Pages (from-to)15933-15939
Number of pages7
JournalJournal of Physical Chemistry C
Volume117
Issue number31
DOIs
Publication statusPublished - 2013 Aug 8

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Decomposition
decomposition
thermal decomposition
Pyrolysis
products
Temperature
temperature

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Mechanistic insights into oxidative decomposition of exo- tetrahydrodicyclopentadiene. / Park, Sun Hee; Kwon, Cheong Hoon; Kim, Joongyeon; Han, Jeong Sik; Jeong, Byung Hun; Han, Hogyu; Kim, Sung Hyun.

In: Journal of Physical Chemistry C, Vol. 117, No. 31, 08.08.2013, p. 15933-15939.

Research output: Contribution to journalArticle

Park, Sun Hee ; Kwon, Cheong Hoon ; Kim, Joongyeon ; Han, Jeong Sik ; Jeong, Byung Hun ; Han, Hogyu ; Kim, Sung Hyun. / Mechanistic insights into oxidative decomposition of exo- tetrahydrodicyclopentadiene. In: Journal of Physical Chemistry C. 2013 ; Vol. 117, No. 31. pp. 15933-15939.
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