Metal effects on the thermal decomposition of exo - tetrahydrodicyclopentadiene

Sun Hee Park, Joongyeon Kim, Jeong Hwan Chun, Wonkeun Chung, Sang Gon Kim, Chang Hun Lee, Byung Hee Chun, Jeong Sik Han, Byung Hun Jeong, Hogyu Han, Sung Hyun Kim

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Abstract

We investigated the thermal decomposition of exo- tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of various metals, Ti, SS316, SS304, Fe, Ni, and Cu. It was found that conversion of exo-THDCP was faster in the presence of metals as compared to in their absence. The order of the metal effects on the increase in the conversion of exo-THDCP was Ti < SS316 < SS304 < Fe < Ni < Cu. The metal-induced increase in the conversion of exo-THDCP was higher at the higher temperature. In addition, the metal-induced increases in the rates of C5-9, C15-, and Csd product formations were higher than those of ≤C4 and C10-14. The composition and crystallinity of metal surfaces were found to be associated with the distinct metal effects on the thermal decomposition of exo-THDCP.

Original languageEnglish
Pages (from-to)4395-4400
Number of pages6
JournalIndustrial and Engineering Chemistry Research
Volume52
Issue number12
DOIs
Publication statusPublished - 2013 Mar 27

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ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

Park, S. H., Kim, J., Chun, J. H., Chung, W., Kim, S. G., Lee, C. H., Chun, B. H., Han, J. S., Jeong, B. H., Han, H., & Kim, S. H. (2013). Metal effects on the thermal decomposition of exo - tetrahydrodicyclopentadiene. Industrial and Engineering Chemistry Research, 52(12), 4395-4400. https://doi.org/10.1021/ie302573n