Metal(loid) immobilization in soils with biochars pyrolyzed in N2 and CO2 environments

Avanthi Deshani Igalavithana, Xiao Yang, Hilda Rizkia Zahra, Filip M.G. Tack, Daniel C.W. Tsang, Eilhann E. Kwon, Yong Sik Ok

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Previous studies indicated that using CO2 as a reaction agent in the pyrolysis of biomass led to an enhanced generation of syngas via direct reaction between volatile organic carbons (VOCs) evolved from the thermal degradation of biomass and CO2. In addition, the physico-chemical properties of biochar in CO2 were modified. In this current study, biochars generated from red pepper stalks in N2 and CO2 (RPS-N and RPS-C, respectively) were tested for their effects on the immobilization of Pb, Cd, Zn, and As in contaminated soils. Soils were incubated for one month with 2.5% of RPS, and two biochars (i.e., RPS-N and RPS-C) at 25 °C. After the incubation period soils were analyzed to determine the amendment effects on the behavior of metal(loid)s. The potential availability and mobility kinetics of metal(loid)s were assessed by single extraction of ammonium acetate and consecutive extraction of calcium chloride, respectively. Sequential extraction was used to further examine potential changes in geochemical fractions of metal(loid)s. The increased soil pH induced by application of the biochars reduced the potentially available Pb, Cd, and Zn, while RPS-C significantly reduced Pb due to the high surface area and aromaticity of RPS-C. However, RPS-C mobilized potentially available As compared to RPS-N due to the increased soil pH. Biochars reduced the mobility kinetics of Pb, Cd, and Zn, and RPS-N effectuated the greatest reduction of As mobility. The RPS-C increased the Fe and Mn oxides, hydroxide, and organically bound Pb, while both biochars and RPS-N increased residual Cd and Zn, and organically bound As, respectively. When considering the two biochars, RPS-C was highly effective for immobilization of Pb in soils, but it had no effect on Cd and Zn and a negative effect on As. In addition, RPS-C significantly increased the total exchangeable cations in soils.

Original languageEnglish
Pages (from-to)1103-1114
Number of pages12
JournalScience of the Total Environment
Volume630
DOIs
Publication statusPublished - 2018 Jul 15

Keywords

  • Black carbon
  • Charcoal
  • Pyrolysis
  • Surface functional groups
  • Toxic metals

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Chemistry
  • Waste Management and Disposal
  • Pollution

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