Microporous Lanthanide-Organic Frameworks with Open Metal Sites: Unexpected Sorption Propensity and Multifunctional Properties

Woo Ram Lee, Dae Won Ryu, Jin Wuk Lee, Jung Hee Yoon, Eui Kwan Koh, Chang Seop Hong

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58 Citations (Scopus)

Abstract

Isostructural lanthanide-organic frameworks were prepared by a solvothermal reaction of the corresponding metal ions and the phosphine-oxide-based tricarboxylate ligand. The gravimetric gas uptake was unexpectedly increased when going from Nd3+ to Gd3+, which is associated with the enhanced surface areas and electrostatic interactions between exposed metal ions and gas molecules with quadrupole moments.

Original languageEnglish
Pages (from-to)4723-4725
Number of pages3
JournalInorganic Chemistry
Volume49
Issue number11
DOIs
Publication statusPublished - 2010 Jun 7

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ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

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