Microporous Lanthanide-Organic Frameworks with Open Metal Sites

Unexpected Sorption Propensity and Multifunctional Properties

Woo Ram Lee, Dae Won Ryu, Jin Wuk Lee, Jung Hee Yoon, Eui Kwan Koh, Chang Seop Hong

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

Isostructural lanthanide-organic frameworks were prepared by a solvothermal reaction of the corresponding metal ions and the phosphine-oxide-based tricarboxylate ligand. The gravimetric gas uptake was unexpectedly increased when going from Nd3+ to Gd3+, which is associated with the enhanced surface areas and electrostatic interactions between exposed metal ions and gas molecules with quadrupole moments.

Original languageEnglish
Pages (from-to)4723-4725
Number of pages3
JournalInorganic Chemistry
Volume49
Issue number11
DOIs
Publication statusPublished - 2010 Jun 7

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Lanthanoid Series Elements
phosphine
sorption
Metal ions
Sorption
metal ions
Gases
Metals
Ions
Coulomb interactions
Static Electricity
gases
phosphines
metals
Oxides
quadrupoles
electrostatics
Ligands
moments
ligands

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Microporous Lanthanide-Organic Frameworks with Open Metal Sites : Unexpected Sorption Propensity and Multifunctional Properties. / Lee, Woo Ram; Ryu, Dae Won; Lee, Jin Wuk; Yoon, Jung Hee; Koh, Eui Kwan; Hong, Chang Seop.

In: Inorganic Chemistry, Vol. 49, No. 11, 07.06.2010, p. 4723-4725.

Research output: Contribution to journalArticle

Lee, Woo Ram ; Ryu, Dae Won ; Lee, Jin Wuk ; Yoon, Jung Hee ; Koh, Eui Kwan ; Hong, Chang Seop. / Microporous Lanthanide-Organic Frameworks with Open Metal Sites : Unexpected Sorption Propensity and Multifunctional Properties. In: Inorganic Chemistry. 2010 ; Vol. 49, No. 11. pp. 4723-4725.
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