TY - JOUR
T1 - MOF-Based Hybrids for Solar Fuel Production
AU - Yoon, Ji Won
AU - Kim, Jae Hyeok
AU - Kim, Changyeon
AU - Jang, Ho Won
AU - Lee, Jong Heun
N1 - Funding Information:
J.W.Y., J.‐H.K., and C.K. contributed equally to this work, which was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. 2020R1A2C3008933 and No. 2018R1A4A1022647).
Publisher Copyright:
© 2021 The Authors. Advanced Energy Materials published by Wiley-VCH GmbH
PY - 2021/7/22
Y1 - 2021/7/22
N2 - Solar fuel production, water splitting, and CO2 reduction by sunlight-assisted catalytic reactions, are attractive and environmentally sustainable approaches used to generate energy. Since many different parameters, including energy band structures, electronic conductivity, surface area, porosity, catalytic activity, and stability of photocatalytic materials, determine the photocatalytic reaction, a single photocatalytic material is often insufficient to fulfill all the requirements. Hybridization to complement the limitations of two or more component materials can provide a viable solution. Particularly, hybridization with metal organic frameworks (MOFs), a new class of materials with excellent controllability of topology, surface area, porosity, morphology, band structure, electrical conductivity, and composition, enables the on-demand design of a myriad of high-performance photocatalysts. Moreover, hybrids formed by MOF-derived materials inherit the distinctive merits from the MOF and offer further diversification for hybrid photocatalysts. Here, the rational design of MOF-based hybrid photocatalysts for solar fuel production is discussed. The synthetic strategies of diverse MOF-based hybrids, the key physicochemical parameters of hybrids to determine photocatalytic and photoelectrochemical reactions, and the mechanisms underlying the synergistic enhancement of solar fuel production are reviewed. Moreover, remaining challenges and future perspectives are addressed.
AB - Solar fuel production, water splitting, and CO2 reduction by sunlight-assisted catalytic reactions, are attractive and environmentally sustainable approaches used to generate energy. Since many different parameters, including energy band structures, electronic conductivity, surface area, porosity, catalytic activity, and stability of photocatalytic materials, determine the photocatalytic reaction, a single photocatalytic material is often insufficient to fulfill all the requirements. Hybridization to complement the limitations of two or more component materials can provide a viable solution. Particularly, hybridization with metal organic frameworks (MOFs), a new class of materials with excellent controllability of topology, surface area, porosity, morphology, band structure, electrical conductivity, and composition, enables the on-demand design of a myriad of high-performance photocatalysts. Moreover, hybrids formed by MOF-derived materials inherit the distinctive merits from the MOF and offer further diversification for hybrid photocatalysts. Here, the rational design of MOF-based hybrid photocatalysts for solar fuel production is discussed. The synthetic strategies of diverse MOF-based hybrids, the key physicochemical parameters of hybrids to determine photocatalytic and photoelectrochemical reactions, and the mechanisms underlying the synergistic enhancement of solar fuel production are reviewed. Moreover, remaining challenges and future perspectives are addressed.
KW - CO reduction
KW - MOF-based hybrids
KW - hydrogen generation
KW - photocatalysts
KW - solar fuel production
UR - http://www.scopus.com/inward/record.url?scp=85099405053&partnerID=8YFLogxK
U2 - 10.1002/aenm.202003052
DO - 10.1002/aenm.202003052
M3 - Review article
AN - SCOPUS:85099405053
VL - 11
JO - Advanced Energy Materials
JF - Advanced Energy Materials
SN - 1614-6832
IS - 27
M1 - 2003052
ER -