N-anthracenylmethyl calix[4]azacrowns as new fluorescent ionophores

Seung H. Yang, Ok J. Shon, Ki M. Park, Shim S. Lee, Ho J. Park, Moon J. Kim, Joung H. Lee, Jong S. Kim

Research output: Contribution to journalArticle

Abstract

Two novel calixarene-based fluoroionophores were synthesized. Their conformations were confirmed to 1,3-alternate by X-ray crystal structures. From CHEF by blocking the PET mechanism in fluorescence spectra, we observed In3+ and Pb2+ion selectivity over other metal ions. For In3+ion, calix[4]-bis-azacrown-5 showed about 20 times more sensitive than calix[4]-mono-azacrown-5 because the source of the binding selectivity comes from the calixarene framework and azacrown ligand by controlling the fluorescence and PET mechanisms associated with the amine moiety.

Original languageEnglish
Pages (from-to)1585-1589
Number of pages5
JournalBulletin of the Korean Chemical Society
Volume23
Issue number11
DOIs
Publication statusPublished - 2002 Nov 20

Keywords

  • Calixarenes
  • Complexation
  • Conformation
  • Fluorescence

ASJC Scopus subject areas

  • Chemistry(all)

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    Yang, S. H., Shon, O. J., Park, K. M., Lee, S. S., Park, H. J., Kim, M. J., Lee, J. H., & Kim, J. S. (2002). N-anthracenylmethyl calix[4]azacrowns as new fluorescent ionophores. Bulletin of the Korean Chemical Society, 23(11), 1585-1589. https://doi.org/10.5012/bkcs.2002.23.11.1585