Nafion/TiO2 nanoparticle decorated thin film composite hollow fiber membrane for efficient removal of SO2 gas

Hyung Jin Park, Umair Hassan Bhatti, Sung Chan Nam, Sung Yeol Park, Ki Bong Lee, Il Hyun Baek

Research output: Contribution to journalArticle

Abstract

In this work, thin film nanocomposite (TFN) membranes for SO2 gas removal have been fabricated by incorporation of PEBAX and Nafion/TiO2 (hereafter referred as Nf/TiO2) nanoparticles on a polyethersulfone hollow fiber membrane substrate. Membrane structure, inner coating, and thickness were confirmed by SEM cross-sectional images. In addition, morphological and structural analyses of the membranes were performed using FTIR, SEM, EDX, TEM, and AFM. To investigate the effects of Nf/TiO2 nanoparticles on the gas permeation performance, four membrane modules with different mass concentrations of Nf/TiO2 – 0.025, 0.050, 0.075, and 0.1 g – were fabricated. The gas permeation experiments were performed with pure SO2, N2, and CO2 gases and a mixed gas (SO2/CO2/N2) within a pressure range of 1–3 bar and feed gas flow rate of 0.03–0.15 L/min. The obtained experimental results suggest that the addition of Nf/TiO2 nanoparticles improved the membrane performance by introducing sulfonate and hydroxyl functional groups to the membrane, and thus increased SO2 permeation and selectivity. The SO2 permeation was found to be 411–1671 GPU in the range of the studied parameters. The ideal selectivities achieved for SO2/N2 and SO2/CO2 were 2928 and 72, respectively. Overall, an SO2 removal efficiency of 93% was achieved by using the Nf/TiO2 incorporated TFN membrane.

Original languageEnglish
Pages (from-to)377-390
Number of pages14
JournalSeparation and Purification Technology
Volume211
DOIs
Publication statusPublished - 2019 Mar 18

Fingerprint

Gases
Nanoparticles
Membranes
Thin films
Fibers
Permeation
Composite materials
Nanocomposites
Membrane structures
Scanning electron microscopy
perfluorosulfonic acid
Hydroxyl Radical
Functional groups
Flow of gases
Energy dispersive spectroscopy
Flow rate
Transmission electron microscopy
Coatings
Substrates
Experiments

Keywords

  • Gas separation
  • Nafion/TiO
  • PEBAX-1657
  • Polyethersulfone
  • Thin film nanocomposite (TFN) hollow fiber membrane

ASJC Scopus subject areas

  • Analytical Chemistry
  • Filtration and Separation

Cite this

Nafion/TiO2 nanoparticle decorated thin film composite hollow fiber membrane for efficient removal of SO2 gas. / Park, Hyung Jin; Bhatti, Umair Hassan; Nam, Sung Chan; Park, Sung Yeol; Lee, Ki Bong; Baek, Il Hyun.

In: Separation and Purification Technology, Vol. 211, 18.03.2019, p. 377-390.

Research output: Contribution to journalArticle

Park, Hyung Jin ; Bhatti, Umair Hassan ; Nam, Sung Chan ; Park, Sung Yeol ; Lee, Ki Bong ; Baek, Il Hyun. / Nafion/TiO2 nanoparticle decorated thin film composite hollow fiber membrane for efficient removal of SO2 gas. In: Separation and Purification Technology. 2019 ; Vol. 211. pp. 377-390.
@article{c6453e1c605148728c2d71e3cb4a1c81,
title = "Nafion/TiO2 nanoparticle decorated thin film composite hollow fiber membrane for efficient removal of SO2 gas",
abstract = "In this work, thin film nanocomposite (TFN) membranes for SO2 gas removal have been fabricated by incorporation of PEBAX and Nafion/TiO2 (hereafter referred as Nf/TiO2) nanoparticles on a polyethersulfone hollow fiber membrane substrate. Membrane structure, inner coating, and thickness were confirmed by SEM cross-sectional images. In addition, morphological and structural analyses of the membranes were performed using FTIR, SEM, EDX, TEM, and AFM. To investigate the effects of Nf/TiO2 nanoparticles on the gas permeation performance, four membrane modules with different mass concentrations of Nf/TiO2 – 0.025, 0.050, 0.075, and 0.1 g – were fabricated. The gas permeation experiments were performed with pure SO2, N2, and CO2 gases and a mixed gas (SO2/CO2/N2) within a pressure range of 1–3 bar and feed gas flow rate of 0.03–0.15 L/min. The obtained experimental results suggest that the addition of Nf/TiO2 nanoparticles improved the membrane performance by introducing sulfonate and hydroxyl functional groups to the membrane, and thus increased SO2 permeation and selectivity. The SO2 permeation was found to be 411–1671 GPU in the range of the studied parameters. The ideal selectivities achieved for SO2/N2 and SO2/CO2 were 2928 and 72, respectively. Overall, an SO2 removal efficiency of 93{\%} was achieved by using the Nf/TiO2 incorporated TFN membrane.",
keywords = "Gas separation, Nafion/TiO, PEBAX-1657, Polyethersulfone, Thin film nanocomposite (TFN) hollow fiber membrane",
author = "Park, {Hyung Jin} and Bhatti, {Umair Hassan} and Nam, {Sung Chan} and Park, {Sung Yeol} and Lee, {Ki Bong} and Baek, {Il Hyun}",
year = "2019",
month = "3",
day = "18",
doi = "10.1016/j.seppur.2018.10.010",
language = "English",
volume = "211",
pages = "377--390",
journal = "Separation and Purification Technology",
issn = "1383-5866",
publisher = "Elsevier",

}

TY - JOUR

T1 - Nafion/TiO2 nanoparticle decorated thin film composite hollow fiber membrane for efficient removal of SO2 gas

AU - Park, Hyung Jin

AU - Bhatti, Umair Hassan

AU - Nam, Sung Chan

AU - Park, Sung Yeol

AU - Lee, Ki Bong

AU - Baek, Il Hyun

PY - 2019/3/18

Y1 - 2019/3/18

N2 - In this work, thin film nanocomposite (TFN) membranes for SO2 gas removal have been fabricated by incorporation of PEBAX and Nafion/TiO2 (hereafter referred as Nf/TiO2) nanoparticles on a polyethersulfone hollow fiber membrane substrate. Membrane structure, inner coating, and thickness were confirmed by SEM cross-sectional images. In addition, morphological and structural analyses of the membranes were performed using FTIR, SEM, EDX, TEM, and AFM. To investigate the effects of Nf/TiO2 nanoparticles on the gas permeation performance, four membrane modules with different mass concentrations of Nf/TiO2 – 0.025, 0.050, 0.075, and 0.1 g – were fabricated. The gas permeation experiments were performed with pure SO2, N2, and CO2 gases and a mixed gas (SO2/CO2/N2) within a pressure range of 1–3 bar and feed gas flow rate of 0.03–0.15 L/min. The obtained experimental results suggest that the addition of Nf/TiO2 nanoparticles improved the membrane performance by introducing sulfonate and hydroxyl functional groups to the membrane, and thus increased SO2 permeation and selectivity. The SO2 permeation was found to be 411–1671 GPU in the range of the studied parameters. The ideal selectivities achieved for SO2/N2 and SO2/CO2 were 2928 and 72, respectively. Overall, an SO2 removal efficiency of 93% was achieved by using the Nf/TiO2 incorporated TFN membrane.

AB - In this work, thin film nanocomposite (TFN) membranes for SO2 gas removal have been fabricated by incorporation of PEBAX and Nafion/TiO2 (hereafter referred as Nf/TiO2) nanoparticles on a polyethersulfone hollow fiber membrane substrate. Membrane structure, inner coating, and thickness were confirmed by SEM cross-sectional images. In addition, morphological and structural analyses of the membranes were performed using FTIR, SEM, EDX, TEM, and AFM. To investigate the effects of Nf/TiO2 nanoparticles on the gas permeation performance, four membrane modules with different mass concentrations of Nf/TiO2 – 0.025, 0.050, 0.075, and 0.1 g – were fabricated. The gas permeation experiments were performed with pure SO2, N2, and CO2 gases and a mixed gas (SO2/CO2/N2) within a pressure range of 1–3 bar and feed gas flow rate of 0.03–0.15 L/min. The obtained experimental results suggest that the addition of Nf/TiO2 nanoparticles improved the membrane performance by introducing sulfonate and hydroxyl functional groups to the membrane, and thus increased SO2 permeation and selectivity. The SO2 permeation was found to be 411–1671 GPU in the range of the studied parameters. The ideal selectivities achieved for SO2/N2 and SO2/CO2 were 2928 and 72, respectively. Overall, an SO2 removal efficiency of 93% was achieved by using the Nf/TiO2 incorporated TFN membrane.

KW - Gas separation

KW - Nafion/TiO

KW - PEBAX-1657

KW - Polyethersulfone

KW - Thin film nanocomposite (TFN) hollow fiber membrane

UR - http://www.scopus.com/inward/record.url?scp=85054452737&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85054452737&partnerID=8YFLogxK

U2 - 10.1016/j.seppur.2018.10.010

DO - 10.1016/j.seppur.2018.10.010

M3 - Article

VL - 211

SP - 377

EP - 390

JO - Separation and Purification Technology

JF - Separation and Purification Technology

SN - 1383-5866

ER -