Nb-doped tio 2: A new compact layer material for TiO 2 dye-sensitized solar cells

Sangwook Lee, Jun Hong Noh, Hyun Soo Han, Dong Kyun Yim, Dong Hoe Kim, Jung Kun Lee, Jin Young Kim, Hyun Suk Jung, Kug Sun Hong

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193 Citations (Scopus)

Abstract

A Nb-doped TiO 2 (NTO) thin film was deposited on a fluorine-doped tin oxide (FTO) electrode by pulsed laser deposition (PLD) and its application as a new compact layer material for dye-sensitized solar cells (DSSCs) was investigated. On the basis of the investigation of the dark current, open circuit voltage (V oc) decay, current-voltage (/- V) characteristics, and electrochemical impedance spectra (EIS), it was found that the NTO layer functioned as both a blocking layer and an ancillary transparent conducting oxide (TCO) layer. As a blocking layer, the NTO layer suppressed the charge recombination from TCO to the electrolyte. In addition, as an ancillary TCO layer, the NTO layer reduced the interfacial resistance between the TiO 2 layer and TCO by forming an ohmic contact. As a result, the overall energy conversion efficiency of the DSSC incorporating the NTO layer was enhanced by 21.2% compared to that with the bare FTO substrate and 4.1% compared to that with the undoped TiO 2 layer, owing to the enhanced charge transfer and collection characteristics of the NTO layer. Our results demonstrated that NTO is a promising alternative to the conventional TiO 2 compact layer in highly efficient DSSCs.

Original languageEnglish
Pages (from-to)6878-6882
Number of pages5
JournalJournal of Physical Chemistry C
Volume113
Issue number16
DOIs
Publication statusPublished - 2009 Apr 23
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

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    Lee, S., Noh, J. H., Han, H. S., Yim, D. K., Kim, D. H., Lee, J. K., Kim, J. Y., Jung, H. S., & Hong, K. S. (2009). Nb-doped tio 2: A new compact layer material for TiO 2 dye-sensitized solar cells. Journal of Physical Chemistry C, 113(16), 6878-6882. https://doi.org/10.1021/jp9002017