Near achiral metal-organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

Kyung Seok Jeong; Bo Hyung Lee; Qiaowei Li; Sang Beom Choi; Jaheon Kim; Nakcheol Jeong

doi:10.1039/c0ce00426j

Near achiral metal-organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

Kyung Seok Jeong, Bo Hyung Lee, Qiaowei Li, Sang Beom Choi, Jaheon Kim, Nakcheol Jeong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A near identical MOF from the reaction between a homochiral ligand and La^III ion to that from racemic ligand was obtained due to the preferential formation of the pseudo-centrosymmetric arrangement in asymmetric units.

Original language	English
Pages (from-to)	1277-1279
Number of pages	3
Journal	CrystEngComm
Volume	13
Issue number	5
DOIs	https://doi.org/10.1039/c0ce00426j
Publication status	Published - 2011 Mar 7

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Near achiral metal-organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit",

abstract = "A near identical MOF from the reaction between a homochiral ligand and LaIII ion to that from racemic ligand was obtained due to the preferential formation of the pseudo-centrosymmetric arrangement in asymmetric units.",

author = "Jeong, {Kyung Seok} and Lee, {Bo Hyung} and Qiaowei Li and Choi, {Sang Beom} and Jaheon Kim and Nakcheol Jeong",

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doi = "10.1039/c0ce00426j",

language = "English",

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publisher = "Royal Society of Chemistry",

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T1 - Near achiral metal-organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

AU - Jeong, Kyung Seok

AU - Lee, Bo Hyung

AU - Li, Qiaowei

AU - Choi, Sang Beom

AU - Kim, Jaheon

AU - Jeong, Nakcheol

PY - 2011/3/7

Y1 - 2011/3/7

N2 - A near identical MOF from the reaction between a homochiral ligand and LaIII ion to that from racemic ligand was obtained due to the preferential formation of the pseudo-centrosymmetric arrangement in asymmetric units.

AB - A near identical MOF from the reaction between a homochiral ligand and LaIII ion to that from racemic ligand was obtained due to the preferential formation of the pseudo-centrosymmetric arrangement in asymmetric units.

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U2 - 10.1039/c0ce00426j

DO - 10.1039/c0ce00426j

M3 - Article

AN - SCOPUS:79951804978

SN - 1466-8033

VL - 13

SP - 1277

EP - 1279

JO - CrystEngComm

JF - CrystEngComm

IS - 5

ER -

Near achiral metal-organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

Abstract

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