New iridium complexes with two pre-organized urea groups and thiourea groups as phosphorescent chemosensors for H2PO4 - and chiral carboxylates

Yinan Li, Yifan Liu, Dayoung Nam, Sungnam Park, Juyoung Yoon, Myung Ho Hyun

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

As a versatile platform for phosphorescent chemosensors, bis(benzylic amine) derivative 6 was synthesized. Two urea groups could be readily introduced for phosphorescent chemosensor 1. A preorganized binding pocket could induce a selective phosphorescence enhancement with H2PO4-. A new iridium complex 2 bearing two thiourea groups as well as glucopyranosyl chiral barriers is reported as a first chiral phosphorescent chemosensor for amino acids.

Original languageEnglish
Pages (from-to)241-246
Number of pages6
JournalDyes and Pigments
Volume100
Issue number1
DOIs
Publication statusPublished - 2014
Externally publishedYes

Keywords

  • Amino acid sensing
  • Anion recognition
  • Chiral recognition
  • Dihydrogen phosphate sensing
  • Iridium complex
  • Phosphorescence chemosensor

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Process Chemistry and Technology

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