Non-Gaussian statistics of amide I mode frequency fluctuation of N-methylacetamide in methanol solution: Linear and nonlinear vibrational spectra

Kijeong Kwac, Hochan Lee, Minhaeng Cho

Research output: Contribution to journalArticle

118 Citations (Scopus)

Abstract

Recently, as a novel tool for structure determination of polypeptides, a variety of two-dimensional (2D) vibrational spectroscopies were experimentally used and theoretically proposed. Among such applications of multidimensional coherent vibrational spectroscopies to various problems, it was shown that the 2D IR pump-probe spectroscopy can be used to directly probe solvation dynamics of amides. This paper presents molecular dynamics simulation results on linear and nonlinear vibrational spectroscopies of the NMA-methanol solution.

Original languageEnglish
Pages (from-to)1477-1490
Number of pages14
JournalJournal of Chemical Physics
Volume120
Issue number3
DOIs
Publication statusPublished - 2004 Jan 15

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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