Nonlinear response functions for birefringence and dichroism measurements in condensed phases

Minhaeng Cho; Graham R. Fleming; Shaul Mukamel

doi:10.1063/1.464931

Nonlinear response functions for birefringence and dichroism measurements in condensed phases

Minhaeng Cho, Graham R. Fleming, Shaul Mukamel

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

The fourth-rank tensorial nonlinear response function which controls the response of a chromophore in the condensed phase to three arbitrarily polarized external fields is calculated. Internal (vibrational and rotational) degrees of freedom are incorporated using wave packets in Liouville space (the doorway/window picture). The rotational contribution of the chromophore is expressed in terms of a conditional probability for the rotational diffusion model. We apply this formalism to transient dichroism and birefringence spectroscopies.

Original language	English
Pages (from-to)	5314-5326
Number of pages	13
Journal	The Journal of chemical physics
Volume	98
Issue number	7
DOIs	https://doi.org/10.1063/1.464931
Publication status	Published - 1993
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.464931

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title = "Nonlinear response functions for birefringence and dichroism measurements in condensed phases",

abstract = "The fourth-rank tensorial nonlinear response function which controls the response of a chromophore in the condensed phase to three arbitrarily polarized external fields is calculated. Internal (vibrational and rotational) degrees of freedom are incorporated using wave packets in Liouville space (the doorway/window picture). The rotational contribution of the chromophore is expressed in terms of a conditional probability for the rotational diffusion model. We apply this formalism to transient dichroism and birefringence spectroscopies.",

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AB - The fourth-rank tensorial nonlinear response function which controls the response of a chromophore in the condensed phase to three arbitrarily polarized external fields is calculated. Internal (vibrational and rotational) degrees of freedom are incorporated using wave packets in Liouville space (the doorway/window picture). The rotational contribution of the chromophore is expressed in terms of a conditional probability for the rotational diffusion model. We apply this formalism to transient dichroism and birefringence spectroscopies.

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Nonlinear response functions for birefringence and dichroism measurements in condensed phases

Abstract

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