Novel 1,3-alternate calix[4]thiacrown ethers

Wonbo Sim, Jai Young Lee, Jongchul Kwon, Moon Jib Kim, Jong Seung Kim

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A series of novel 1,3-alternate calix[4]-mono-thiacrown and -bis-thiacrowns were synthesized within good yields. The three dimensional 1,3-alternate conformation was confirmed by X-ray crystal structure. From the results of two phase extraction and NMR studies on the ligand-metal complex, one can conclude that the calix[4]thiacrown ethers showed the very high selectivity for silver ion over other metal ions by an electrostatic interaction between sulfur atom and silver ion and by a π-metal complexation.

Original languageEnglish
Pages (from-to)879-883
Number of pages5
JournalBulletin of the Korean Chemical Society
Volume23
Issue number6
DOIs
Publication statusPublished - 2002 Jun 20

Keywords

  • Calix[4]-bis-thiacrown
  • Calix[4]thiacrown ether
  • Complexation
  • Picrate extraction

ASJC Scopus subject areas

  • Chemistry(all)

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