Novel [60]fullerene-assisted ortho-phosphanation on a tetrairidium butterfly framework

Bo Keun Park, M. Arzu Miah, Gaehang Lee, Youn Jaung Cho, Kwangyeol Lee, Sangwoo Park, Moon Gun Choi, Joon T. Park

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A mono- to di- and triphosphane transformation occurs on treatment of [Ir4(CO)9(PPh3)3] (1) with C 60 to successively afford 2 and 3. The noninnocent, multifunctional C60 ligand plays a crucial role in transforming three PPh3 ligands into a μ3-PPh2(o-C6H4) P(o-C6H4) PPh(η1-o-C6H 4) triphosphane ligand by a series of ortho-phosphanation and ortho-metalation processes on the Ir4 cluster framework.

Original languageEnglish
Pages (from-to)1712-1714
Number of pages3
JournalAngewandte Chemie - International Edition
Volume43
Issue number13
DOIs
Publication statusPublished - 2004 Mar 19

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Keywords

  • Cluster compounds
  • Fullerenes
  • Iridium
  • P ligands
  • Phosphanation

ASJC Scopus subject areas

  • Chemistry(all)

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